Evidence map›Paper›PMID 32681039›Full record

ArticleNature communications2020

Unimolecularly thick monosheets of vinyl polymers fabricated in metal-organic frameworks.

Nobuhiko Hosono, Shuto Mochizuki, Yuki Hayashi, Takashi Uemura

Open access · goldAbstract read
In one paragraph

Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
2.1field-weighted citation impact, top 13% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed, 43 citations in OpenAlex.

  1. A Bifunctional UiO-66 Platform Enabled by Schiff-Base Engineering for COSmall (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  2. Reticular Frameworks for Advanced Polymer Materials.Advanced materials (Deerfield Beach, Fla.) · 2026
    Review
  3. Article
  4. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 3 institutions in 1 country.

Nobuhiko HosonoDepartment of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba, 277-8561, Japan.ORCID http://orcid.org/0000-0002-4145-0046
Shuto MochizukiDepartment of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba, 277-8561, Japan.
Yuki HayashiDepartment of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba, 277-8561, Japan.
Takashi UemuraDepartment of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba, 277-8561, Japan. t-uemura@k.u-tokyo.ac.jp.ORCID http://orcid.org/0000-0002-1357-3196
The University of Tokyo · JPJapan Science and Technology Agency · JPKyoto University · JP

Funding

MEXT | JST | Core Research for Evolutional Science and Technology (CREST) JPMJCR1321Ministry of Education, Culture, Sports, Science and Technology (MEXT) JP16H06517
6 · The paper itself

Abstract

Polymers with two-dimensional (2D) network topologies are currently gaining significant attention due to their unique properties that originate from their regulated conformations. However, in contrast to conventional 1D- and 3D-networked macromolecules, the synthesis of such 2D networks provides challenges for polymer chemists because of the nature of the networking polymerisation reaction, which occurs in a spatially random fashion when conventional solution-phase synthesis is performed. Here we report a versatile synthesis of polymeric monosheets with unimolecularly thick networking architectures by exploiting the 2D nanospaces of metal-organic frameworks (MOFs) as reaction templates. Crosslinking radical polymerisation in the 2D nanospaces of pillared-layer-type MOFs affords monosheets of typical vinyl polymers and can be carried out on the gram scale. Remarkably, the prepared polymer monosheets are highly soluble in organic solvents and show atypical thermal and rheological properties that result from their 2D-regulated conformations that cannot be adopted by their 1D or 3D analogues.

Identifiers

PMID32681039
PMCPMC7367882
OpenAlexW3042737601

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.