ArticleAngewandte Chemie (International ed. in English)2020
Photo-Induced Ruthenium-Catalyzed C-H Arylations at Ambient Temperature.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Arene Ruthenium(II) Carboxylates for C─H Alkylations and Arylations at Near Room Temperature.Angewandte Chemie (International ed. in English) · 2025Article
- Photo-induced ruthenium-catalyzed alkene C-H-arylation at room temperature.Chemical communications (Cambridge, England) · 2025Article
- Photoinduced Ruthenium-CatalyzedACS catalysis · 2025Article
- Bis-Cycloruthenated Complexes in Visible Light-Induced C-H Alkylation with Epoxides.Journal of the American Chemical Society · 2025Article
- Photocatalytic regioselective C-H bond functionalizations in arenes.Chemical science · 2025Review
- Photoinduced C-H arylation of 1,3-azolesChemical science · 2024Article
- Cyclometalated and NNN Terpyridine Ruthenium Photocatalysts and Their Cytotoxic Activity.Molecules (Basel, Switzerland) · 2024Article
- The crucial role of silver(I)-salts as additives in C-H activation reactions: overall analysis of their versatility and applicability.Chemical Society reviews · 2023Review
- Transition-Metal-Catalyzed C-H Bond Activation for the Formation of C-C Bonds in Complex Molecules.Chemical reviews · 2023Review
- Improving the sustainability of the ruthenium-catalysedGreen chemistry : an international journal and green chemistry resource : GC · 2023Article
- Terpyridine Diphosphine Ruthenium Complexes as Efficient Photocatalysts for the Transfer Hydrogenation of Carbonyl Compounds.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Ru(II)-Catalyzed Hydroarylation of in situ Generated 3,3,3-Trifluoro-1-propyne by C-H Bond Activation: A Facile and Practical Access to β-Trifluoromethylstyrenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Photo-Induced Ruthenium-Catalyzed Double Remote C(spAngewandte Chemie (International ed. in English) · 2022Article
- Visible-Light-Induced, Single-Metal-Catalyzed, Directed C-H Functionalization: Metal-Substrate-Bound Complexes as Light-Harvesting Agents.Angewandte Chemie (International ed. in English) · 2022Review
- Enantioselective Cytotoxicity of Chiral Diphosphine Ruthenium(II) Complexes Against Cancer Cells.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Organometallic catalysis under visible light activation: benefits and preliminary rationales.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2022Article
- Catalysis with cycloruthenated complexes.Chemical science · 2022Review
- C-H activation by immobilized heterogeneous photocatalysts.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2021Article
- Photo-Induced Ruthenium-Catalyzed C-H Benzylations and Allylations at Room Temperature.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Photo-Induced Ruthenium-Catalyzed C-H Arylations at Ambient Temperature.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
Ambient temperature ruthenium-catalyzed C-H arylations were accomplished by visible light without additional photocatalysts. The robustness of the ruthenium-catalyzed C-H functionalization protocol was reflected by a broad range of sensitive functional groups and synthetically useful pyrazoles, triazoles and sensitive nucleosides and nucleotides, as well as multifold C-H functionalizations. Biscyclometalated ruthenium complexes were identified as the key intermediates in the photoredox ruthenium catalysis by detailed computational and experimental mechanistic analysis. Calculations suggested that the in situ formed photoactive ruthenium species preferably underwent an inner-sphere electron transfer.
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