Evidence map›Paper›PMID 32652750›Full record

ArticleAngewandte Chemie (International ed. in English)2020

Synergy of Electrostatic and π-π Interactions in the Realization of Nanoscale Artificial Photosynthetic Model Systems.

Eduardo Anaya-Plaza, Jan Joseph, Stefan Bauroth, Maximilian Wagner, Christian Dolle, Michael Sekita, Franziska Gröhn, Erdmann Spiecker, Timothy Clark, Andrés de la Escosura and 2 more

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.

0numbers the graph read from it
0cells of the map it votes in
11citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

11 citing papers in PubMed.

  1. Review
  2. Mechanochemical SChemSusChem · 2026
    Article
  3. Article
  4. Article
  5. Article
  6. A Greener Route to Blue: Solid-State Synthesis of Phthalocyanines.Angewandte Chemie (International ed. in English) · 2022
    Article
  7. A bioinspired hollow g-CChemical science · 2022
    Article
  8. Article
  9. Article
  10. Article
  11. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Eduardo Anaya-PlazaDepartment of Organic Chemistry, Universidad Autónoma de Madrid (UAM), c/ Francisco Tomás y Valiente 7, Cantoblanco, 28049, Madrid, Spain.ORCID 0000-0001-9944-6907
Jan JosephDepartment of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 91058, Erlangen, Germany.
Stefan BaurothDepartment of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 91058, Erlangen, Germany.
Maximilian WagnerDepartment of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 91058, Erlangen, Germany.
Christian DolleDepartment of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 91058, Erlangen, Germany.
Michael SekitaDepartment of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 91058, Erlangen, Germany.
Franziska GröhnDepartment of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 91058, Erlangen, Germany.
Erdmann SpieckerDepartment of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 91058, Erlangen, Germany.
Timothy ClarkDepartment of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 91058, Erlangen, Germany.
Andrés de la EscosuraDepartment of Organic Chemistry, Universidad Autónoma de Madrid (UAM), c/ Francisco Tomás y Valiente 7, Cantoblanco, 28049, Madrid, Spain.ORCID 0000-0002-0928-8317
Dirk M GuldiDepartment of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 91058, Erlangen, Germany.
Tomás TorresDepartment of Organic Chemistry, Universidad Autónoma de Madrid (UAM), c/ Francisco Tomás y Valiente 7, Cantoblanco, 28049, Madrid, Spain.ORCID 0000-0001-9335-6935

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

In the scientific race to build up photoactive electron donor-acceptor systems with increasing efficiencies, little is known about the interplay of their building blocks when integrated into supramolecular nanoscale arrays, particularly in aqueous environments. Here, we describe an aqueous donor-acceptor ensemble whose emergence as a nanoscale material renders it remarkably stable and efficient. We have focused on a tetracationic zinc phthalocyanine (ZnPc) featuring pyrenes, which shows an unprecedented mode of aggregation, driven by subtle cooperation between electrostatic and π-π interactions. Our studies demonstrate monocrystalline growth in solution and a symmetry-breaking intermolecular charge transfer between adjacent ZnPcs upon photoexcitation. Immobilizing a negatively charged fullerene (C

Indexed as

artificial photosynthesisfullerenesnanoscale self-assemblyphthalocyanines

Identifiers

PMID32652750
PMCPMC7590087

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.