Evidence map›Paper›PMID 32627908›Full record

ArticleAngewandte Chemie (International ed. in English)2020

Inverse Vulcanization of Styrylethyltrimethoxysilane-Coated Surfaces, Particles, and Crosslinked Materials.

Johannes M Scheiger, Chatrawee Direksilp, Patricia Falkenstein, Alexander Welle, Meike Koenig, Stefan Heissler, Jörg Matysik, Pavel A Levkin, Patrick Theato

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Johannes M ScheigerInstitute of Chemical Technology and Polymer Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstrasse 20, 76131, Karlsruhe, Germany.ORCID http://orcid.org/0000-0003-4950-8342
Chatrawee DireksilpThe Petroleum and Petrochemical College (PPC), Chulalongkorn University, Soi Chulalongkorn 12, Phayathai road, Pathumwan, Bangkok, 10330, Thailand.
Patricia FalkensteinInstitute of Analytical Chemistry, Leipzig University, Linnéstrasse 3, 04103, Leipzig, Germany.
Alexander WelleInstitute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (Campus North), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.
Meike KoenigInstitute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (Campus North), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.
Stefan HeisslerInstitute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (Campus North), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.
Jörg MatysikInstitute of Analytical Chemistry, Leipzig University, Linnéstrasse 3, 04103, Leipzig, Germany.
Pavel A LevkinInstitute of Biological and Chemical Systems-Functional Materials Systems (IBCS-FMS), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.
Patrick TheatoInstitute of Chemical Technology and Polymer Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstrasse 20, 76131, Karlsruhe, Germany.ORCID http://orcid.org/0000-0002-4562-9254

Funding

Deutsche Bundesstiftung UmweltDFG 406232485
6 · The paper itself

Abstract

Sulfur as a side product of natural gas and oil refining is an underused resource. Converting landfilled sulfur waste into materials merges the ecological imperative of resource efficiency with economic considerations. A strategy to convert sulfur into polymeric materials is the inverse vulcanization reaction of sulfur with alkenes. However, the materials formed are of limited applicability, because they need to be cured at high temperatures (>130 °C) for many hours. Herein, we report the reaction of elemental sulfur with styrylethyltrimethoxysilane. Marrying the inverse vulcanization and silane chemistry yielded high sulfur content polysilanes, which could be cured via room temperature polycondensation to obtain coated surfaces, particles, and crosslinked materials. The polycondensation was triggered by hydrolysis of poly(sulfur-r-styrylethyltrimethoxysilane) (poly(S

Indexed as

alkoxy silanescoatingsinverse vulcanizationmercury remediationsulfur

Identifiers

PMID32627908
PMCPMC7589442

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.