Evidence map›Paper›PMID 32598845›Full record

ArticleJournal of the American Chemical Society2020

A W/Cu Synthetic Model for the Mo/Cu Cofactor of Aerobic CODH Indicates That Biochemical CO Oxidation Requires a Frustrated Lewis Acid/Base Pair.

Dibbendu Ghosh, Soumen Sinhababu, Bernard D Santarsiero, Neal P Mankad

Open access · greenAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.

0numbers the graph read from it
0cells of the map it votes in
13citing papers in PubMed
1.3field-weighted citation impact, top 21% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

13 citing papers in PubMed, 36 citations in OpenAlex.

  1. Article
  2. Article
  3. Transformation of tetranuclear [{MoOChemical communications (Cambridge, England) · 2026
    Article
  4. Heterodinuclear Cu(I)/Mo(VI) chemistry with bifunctional dibenzobarrelene ligands.Dalton transactions (Cambridge, England : 2003) · 2025
    Article
  5. Understanding the role of negative charge in the scaffold of an artificial enzyme for COJournal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2024
    Article
  6. COChemical communications (Cambridge, England) · 2024
    Article
  7. Article
  8. Article
  9. Review
  10. Review
  11. Can Water Act as a Nucleophile in CO Oxidation Catalysed by Mo/Cu CO-Dehydrogenase? Answers from Theory.Chemphyschem : a European journal of chemical physics and physical chemistry · 2022
    Article
  12. Sensitized Photocatalytic COFrontiers in chemistry · 2021
    Article
  13. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 1 institution in 1 country.

Dibbendu GhoshDepartment of Chemistry, University of Illinois at Chicago, 845 W. Taylor Street, Chicago, Illinois 60607, United States.ORCID 0000-0001-6658-0966
Soumen SinhababuDepartment of Chemistry, University of Illinois at Chicago, 845 W. Taylor Street, Chicago, Illinois 60607, United States.ORCID 0000-0003-2149-7450
Bernard D SantarsieroDepartment of Pharmaceutical Sciences, College of Pharmacy, 833 S. Wood Street, Chicago, Illinois 60612, United States.ORCID 0000-0002-9032-9699
Neal P MankadDepartment of Chemistry, University of Illinois at Chicago, 845 W. Taylor Street, Chicago, Illinois 60607, United States.ORCID 0000-0001-6923-5164
University of Illinois Chicago · US

Funding

Copper Sulfide Model Complexes for Small Molecule ActivationR01GM116820 · NIGMS · UNIVERSITY OF ILLINOIS AT CHICAGO · PI MANKAD, NEAL P · 2016 to 2020
$1.1M
NIGMS NIH HHS R01 GM116820
6 · The paper itself

Abstract

Constructing synthetic models of the Mo/Cu active site of aerobic carbon monoxide dehydrogenase (CODH) has been a long-standing synthetic challenge thought to be crucial for understanding how atmospheric concentrations of CO and CO

Indexed as

Aldehyde OxidoreductasesBase PairingCarbon MonoxideCopperDensity Functional TheoryLewis AcidsModels, MolecularMolecular StructureMolybdenumMultienzyme ComplexesOxidation-ReductionTungstenAldehyde OxidoreductasesCarbon Monoxidecarbon monoxide dehydrogenaseCopperLewis AcidsMolybdenumMultienzyme ComplexesTungsten

Identifiers

PMID32598845
PMCPMC9307224
OpenAlexW3037407273

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.