Evidence map›Paper›PMID 32588633›Full record

ArticleOrganic letters2020

Hexafluoroisopropanol-Promoted Disulfidation and Diselenation of Alkyne, Alkene, and Allene.

Chiyu Wei, Ying He, Jin Wang, Xiaohan Ye, Lukasz Wojtas, Xiaodong Shi

Open access · greenAbstract read
In one paragraph

Article in Organic letters, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
2.4field-weighted citation impact, top 11% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 39 citations in OpenAlex.

  1. Silylium-Ion-Initiated Disulfidation of Internal Alkynes With Disulfides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 2 institutions in 2 countries.

Chiyu WeiDepartment of Chemistry, University of South Florida, Tampa, Florida 33620, United States.
Ying HeDepartment of Chemistry, University of South Florida, Tampa, Florida 33620, United States.
Jin WangCollege of Chemistry, Chemical Engineering and Material Science, Shandong Normal University, Jinan, Shandong 250014, China.
Xiaohan YeDepartment of Chemistry, University of South Florida, Tampa, Florida 33620, United States.
Lukasz WojtasDepartment of Chemistry, University of South Florida, Tampa, Florida 33620, United States.
Xiaodong ShiDepartment of Chemistry, University of South Florida, Tampa, Florida 33620, United States.ORCID 0000-0002-3189-1315
University of South Florida · USShandong Normal University · CN

Funding

Achieving challenging coupling with gold redox catalysisR01GM120240 · NIGMS · UNIVERSITY OF SOUTH FLORIDA · PI SHI, XIAODONG · 2016 to 2020
$1.6M
NIGMS NIH HHS R01 GM120240
6 · The paper itself

Abstract

Hexafluoroisopropanol (HFIP)-promoted disulfidation and diselenation of C-C unsaturated bonds is reported. Reactions of unactivated alkyne, alkene, and allene, respectively, with disulfides or diselenides in HFIP led to desired products in good to excellent yields (up to 96%). In contrast, other solvents, such as isopropanol and dichloroethane, could not promote the same reaction. This method revealed an example of HFIP-promoted transformations under the mild conditions, which greatly highlighted the unique reactivity of this special solvent.

Indexed as

AlkenesAlkynesCatalysisHydrocarbons, FluorinatedOrganoselenium CompoundsPropanolsSolventsSulfidesAlkenesAlkyneshexafluoroisopropanolHydrocarbons, FluorinatedOrganoselenium CompoundsPropanolsSolventsSulfides

Identifiers

PMID32588633
PMCPMC10264211
OpenAlexW3037361200

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.