ArticleScience advances2020
Tunable structural color of bottlebrush block copolymers through direct-write 3D printing from solution.
Article in Science advances, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 39 papers.
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Who cites it
39 citing papers in PubMed.
- Microbeam SAXS Reveals Flow-Induced Nanostructural Heterogeneity and Tilted Domains in 3D-Printed Block Copolymers.Macromolecules · 2026Article
- Tuning the Mechanical Properties of Crosslinked Copolymers via Sequence and Solvent-Selective Swelling for Vat Photopolymerization.Angewandte Chemie (International ed. in English) · 2026Article
- Freeform Manufacturing of Plant-Based Structural Colors for Scalable Photonic and Mechanochromic Devices.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Advances in Strategies for Colloidal Self-Assembly.Chemical reviews · 2026Review
- Inverse design of structural colours in polymeric films with crystallization-induced reversible thermochromism.Nature communications · 2025Article
- Molecular Structure of Foldable Bottlebrush Polymers in Melts.Macromolecules · 2025Article
- Synthesis and Solvent Free DLP 3D Printing of Degradable Poly(Allyl Glycidyl Ether Succinate).Angewandte Chemie (International ed. in English) · 2025Article
- Article
- Bottlebrush Networks: A Primer for Advanced Architectures.Angewandte Chemie (International ed. in English) · 2024Review
- Achieving High-Temperature Stable Structural Color through Nanostructuring in Polymer-Derived Ceramics.ACS applied materials & interfaces · 2024Article
- Direct-ink-write cross-linkable bottlebrush block copolymers for on-the-fly control of structural color.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Tuning disorder in structurally colored bioinspired photonic glasses.Soft matter · 2024Article
- Functional PDMS Elastomers: Bulk Composites, Surface Engineering, and Precision Fabrication.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Review
- Emergence and inversion of chirality in hierarchical assemblies of CdS nanocrystal fibers.Science advances · 2023Article
- Article
- Rational control of meniscus-guided coating for organic photovoltaics.Science advances · 2023Article
- 3D printing of responsive chiral photonic nanostructures.Proceedings of the National Academy of Sciences of the United States of America · 2023Article
- Conductive and elastic bottlebrush elastomers for ultrasoft electronics.Nature communications · 2023Article
- Review
- Autonomous discovery of emergent morphologies in directed self-assembly of block copolymer blends.Science advances · 2023Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Additive manufacturing of functional materials is limited by control of microstructure and assembly at the nanoscale. In this work, we integrate nonequilibrium self-assembly with direct-write three-dimensional (3D) printing to prepare bottlebrush block copolymer (BBCP) photonic crystals (PCs) with tunable structure color. After varying deposition conditions during printing of a single ink solution, peak reflected wavelength for BBCP PCs span a range of 403 to 626 nm (blue to red), corresponding to an estimated change in d-spacing of >70 nm (Bragg- Snell equation). Physical characterization confirms that these vivid optical effects are underpinned by tuning of lamellar domain spacing, which we attribute to modulation of polymer conformation. Using in situ optical microscopy and solvent-vapor annealing, we identify kinetic trapping of metastable microstructures during printing as the mechanism for domain size control. More generally, we present a robust processing scheme with potential for on-the-fly property tuning of a variety of functional materials.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.