ArticleChemphyschem : a European journal of chemical physics and physical chemistry2020
Single Quality Factor for Enthalpy-Entropy Compensation, Isoequilibrium and Isokinetic Relationships.
Article in Chemphyschem : a European journal of chemical physics and physical chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
4 citing papers in PubMed.
- Tuning TiFeACS applied energy materials · 2025Article
- Grain-growth mediated hydrogen sorption kinetics and compensation effect in single Pd nanoparticles.Nature communications · 2021Article
- Simple Accurate Verification of Enthalpy-Entropy Compensation and Isoequilibrium Relationship.Chemphyschem : a European journal of chemical physics and physical chemistry · 2021Article
- Single Quality Factor for Enthalpy-Entropy Compensation, Isoequilibrium and Isokinetic Relationships.Chemphyschem : a European journal of chemical physics and physical chemistry · 2020Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Enthalpy-entropy compensation (EEC) is very often encountered in chemistry, biology and physics. Its origin is widely discussed since it would allow, for example, a very accurate tuning of the thermodynamic properties as a function of the reactants. However, EEC is often discarded as a statistical artefact, especially when only a limited temperature range is considered. We show that the likeliness of a statistical origin of an EEC can be established with a compensation quality factor (CQF) that depends only on the measured enthalpies and entropies and the experimental temperature range. This is directly derived from a comparison of the CQF with threshold values obtained from a large number of simulations with randomly generated Van 't Hoff plots. The value of CQF is furthermore a direct measure of the existence of a genuine isoequilibrium or isokinetic relationship.
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Registered trials
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