ArticleInternational journal of molecular sciences2020
Enzymatic Synthesis of Glucose Monodecanoate in a Hydrophobic Deep Eutectic Solvent.
Article in International journal of molecular sciences, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Selective Enzymatic Synthesis of Glucose Fatty Acid Esters in a Choline Chloride-Glucose Reactive Deep Eutectic Solvent.ChemSusChem · 2026Article
- Whole-cell-catalyzed cinnamoylation of phillyrin in natural deep eutectic solvent-based co-solvent systems.Frontiers in microbiology · 2026Article
- Sugar Esters of Fatty Acids: Chemo-Enzymatic Synthesis and Biological Activity.Molecules (Basel, Switzerland) · 2025Review
- Designed Reactive Natural Deep Eutectic Solvents for Lipase-Catalyzed Esterification.Molecules (Basel, Switzerland) · 2025Article
- Insights into Carvone: Fatty Acid Hydrophobic NADES for Alkane Solubilization.Energy & fuels : an American Chemical Society journal · 2024Article
- Solvent Tolerance Improvement of Lipases Enhanced Their Applications: State of the Art.Molecules (Basel, Switzerland) · 2024Review
- Intensification of Enzymatic Sorbityl Laurate Production in Dissolved and Neat Systems under Conventional and Microwave Heating.ACS omega · 2024Article
- Latest Trends in Lipase-Catalyzed Synthesis of Ester Carbohydrate Surfactants: From Key Parameters to Opportunities and Future Development.International journal of molecular sciences · 2024Review
- Development and Characterization of Pickering Emulsion Stabilized by Walnut Protein Isolate Nanoparticles.Molecules (Basel, Switzerland) · 2023Article
- Combination of Enzymes and Deep Eutectic Solvents as Powerful Toolbox for Organic Synthesis.Molecules (Basel, Switzerland) · 2023Review
- Enhanced Bioactivity of Tailor-Made Glycolipid Enriched Manuka Honey.International journal of molecular sciences · 2022Article
- Lipase-Mediated Mechanoenzymatic Synthesis of Sugar Esters in Dissolved Unconventional and Neat Reaction Systems.ACS sustainable chemistry & engineering · 2022Article
- Parameters Influencing Lipase-Catalyzed Glycolipid Synthesis by (Trans-)Esterification Reaction.Advances in biochemical engineering/biotechnology · 2022Review
- Ultrasound-assisted enzymatic synthesis of xylitol fatty acid esters in solvent-free conditions.Ultrasonics sonochemistry · 2021Article
- Lipase-Catalyzed Production of Sorbitol Laurate in a "2-in-1" Deep Eutectic System: Factors Affecting the Synthesis and Scalability.Molecules (Basel, Switzerland) · 2021Article
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3 authors.
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Abstract
Environmentally friendly and biodegradable reaction media are an important part of a sustainable glycolipid production in the transition to green chemistry. Deep eutectic solvents (DESs) are an ecofriendly alternative to organic solvents. So far, only hydrophilic DESs were considered for enzymatic glycolipid synthesis. In this study, a hydrophobic DES consisting of (-)-menthol and decanoic acid is presented for the first time as an alternative to hydrophilic DES. The yields in the newly introduced hydrophobic DES are significantly higher than in hydrophilic DESs. Different reaction parameters were investigated to optimize the synthesis further. Twenty milligrams per milliliter iCalB and 0.5 M glucose resulted in the highest initial reaction velocity for the esterification reaction, while the highest initial reaction velocity was achieved with 1.5 M glucose in the transesterification reaction. The enzyme was proven to be reusable for at least five cycles without significant loss of activity.
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