ArticleThe European physical journal. E, Soft matter2020
Phase stability of dispersions of hollow silica nanocubes mediated by non-adsorbing polymers.
Article in The European physical journal. E, Soft matter, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Although there are theoretical predictions (Eur. Phys. J. E 41, 110 (2018)) for the rich-phase behaviour of colloidal cubes mixed with non-adsorbing polymers, a thorough verification of this phase behaviour is still underway; experimental studies on mixtures of cubes and non-adsorbing polymers in bulk are scarce. In this paper, mixtures of hollow silica nanocubes and linear polystyrene in N,-N-dimethylformamide are used to measure the structure factor of the colloidal cubes as a function of non-adsorbing polymer concentration. Together with visual observations these structure factors enabled us to assess the depletion-mediated phase stability of cube-polymer mixtures. The theoretical and experimental phase boundaries for cube-depletant mixtures are in remarkable agreement, despite the simplifications underlying the theory employed.
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