Evidence map›Paper›PMID 32544289›Full record

ArticleAngewandte Chemie (International ed. in English)2020

Dynamic Covalent Formation of Concave Disulfide Macrocycles Mechanically Interlocked with Single-Walled Carbon Nanotubes.

Bugga Balakrishna, Arjun Menon, Kecheng Cao, Sebastian Gsänger, Sebastian B Beil, Julia Villalva, Oleksandr Shyshov, Oliver Martin, Andreas Hirsch, Bernd Meyer and 3 more

Open access · greenAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.

0numbers the graph read from it
0cells of the map it votes in
11citing papers in PubMed
2.8field-weighted citation impact, top 8% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

11 citing papers in PubMed, 52 citations in OpenAlex.

  1. Photocatalytically Active Mechanically Interlocked Carbon Nanotubes.Small (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  2. Article
  3. Article
  4. Article
  5. Dynamic covalent synthesis.Chemical science · 2024
    Review
  6. Review
  7. Article
  8. Anion-assisted amidinium exchange and metathesis.Chemical communications (Cambridge, England) · 2022
    Article
  9. Single-Walled Carbon Nanotubes Encapsulated within Metallacycles.Angewandte Chemie (International ed. in English) · 2022
    Article
  10. Article
  11. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors at 2 institutions in 1 country.

Bugga BalakrishnaInstitute of Organic Chemistry, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.ORCID http://orcid.org/0000-0003-0326-1401
Arjun MenonDepartment of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials, Friedrich-Alexander University Erlangen-Nürnberg, Egerlandstrasse 3, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0001-7977-1745
Kecheng CaoElectron Microscopy of Materials Science, Central Facility for Electron Microscopy, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.ORCID http://orcid.org/0000-0002-7180-7237
Sebastian GsängerInterdisciplinary Center for Molecular Materials (ICMM) & Computer-Chemistry-Center (CCC), Friedrich-Alexander University Erlangen-Nürnberg, Nägelsbachstrasse 25, 91052, Erlangen, Germany.
Sebastian B BeilInstitute of Organic Chemistry, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.ORCID http://orcid.org/0000-0003-0373-3843
Julia VillalvaInstitute of Organic Chemistry, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.ORCID http://orcid.org/0000-0002-5628-2006
Oleksandr ShyshovInstitute of Organic Chemistry, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.ORCID http://orcid.org/0000-0001-7172-4039
Oliver MartinDepartment of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander University Erlangen-Nürnberg, Nikolaus-Fiebiger-Strasse 10, 91058, Erlangen, Germany.
Andreas HirschDepartment of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander University Erlangen-Nürnberg, Nikolaus-Fiebiger-Strasse 10, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0003-1458-8872
Bernd MeyerInterdisciplinary Center for Molecular Materials (ICMM) & Computer-Chemistry-Center (CCC), Friedrich-Alexander University Erlangen-Nürnberg, Nägelsbachstrasse 25, 91052, Erlangen, Germany.ORCID http://orcid.org/0000-0002-3481-8009
Ute KaiserElectron Microscopy of Materials Science, Central Facility for Electron Microscopy, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.ORCID http://orcid.org/0000-0003-0582-4044
Dirk M GuldiDepartment of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials, Friedrich-Alexander University Erlangen-Nürnberg, Egerlandstrasse 3, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0002-3960-1765
Max von DeliusInstitute of Organic Chemistry, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.ORCID http://orcid.org/0000-0003-1852-2969
Universität Ulm · DEFriedrich-Alexander-Universität Erlangen-Nürnberg · DE

Funding

Deutsche Forschungsgemeinschaft 182849149-SFB953 "Synthetic Carbon Allotropes"Deutsche Forschungsgemeinschaft 364549901 - TRR 234Deutscher Akademischer Austauschdienst 91653809
6 · The paper itself

Abstract

The formation of discrete macrocycles wrapped around single-walled carbon nanotubes (SWCNTs) has recently emerged as an appealing strategy to functionalize these carbon nanomaterials and modify their properties. Here, we demonstrate that the reversible disulfide exchange reaction, which proceeds under mild conditions, can install relatively large amounts of mechanically interlocked disulfide macrocycles on the one-dimensional nanotubes. Size-selective functionalization of a mixture of SWCNTs of different diameters were observed, presumably arising from error correction and the presence of relatively rigid, curved π-systems in the key building blocks. A combination of UV/Vis/NIR, Raman, photoluminescence excitation, and transient absorption spectroscopy indicated that the small (6,4)-SWCNTs were predominantly functionalized by the small macrocycles 1

Indexed as

curved π-systemsdisulfide exchangemechanically interlocked architecturessingle-walled carbon nanotubessupramolecular chemistry

Identifiers

PMID32544289
PMCPMC7590186
OpenAlexW3034464655

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.