ArticleAngewandte Chemie (International ed. in English)2020
Supramolecular Packing Drives Morphological Transitions of Charged Surfactant Micelles.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Raman scattering spectroscopic analysis on the structural changes in the micelles of a CTAB-NapTS system.Analytical sciences : the international journal of the Japan Society for Analytical Chemistry · 2026Article
- Role of Acids in Stabilizing Reverse Micelles: Insights from Dodecyl Sulfate.Langmuir : the ACS journal of surfaces and colloids · 2026Article
- Challenging the dry core paradigm: hydrated reactivity emerges within micellar cores.Chemical science · 2026Article
- Self-Assembly of Unconventional Triphenylene-Based Frustrated Amphiphile in Solution.Langmuir : the ACS journal of surfaces and colloids · 2026Article
- Detergent-Triggered Membrane Remodelling Monitored via Intramembrane Fluorescence Dequenching.ACS omega · 2026Article
- Evaluation of the Emulsification Properties of Marine-Derived Rhamnolipids for Encapsulation: A Comparison with Commercial Surfactants.Biomolecules · 2025Article
- GPU Accelerated Hybrid Particle-Field Molecular Dynamics: Multi-Node/Multi-GPU Implementation and Large-Scale Benchmarks of the OCCAM Code.Journal of computational chemistry · 2025Article
- Article
- Heating-Induced Switching to Hierarchical Liquid Crystallinity Combining Colloidal and Molecular Order in Zwitterionic Molecules.ACS omega · 2023Article
- A hierarchical spatial assembly approach of silica-polymer composites leads to versatile silica/carbon nanoparticles.Science advances · 2023Article
- Bacterial lipids drive compartmentalization on the nanoscale.Nanoscale · 2023Article
- HylleraasMD: A Domain Decomposition-Based Hybrid Particle-Field Software for Multiscale Simulations of Soft Matter.Journal of chemical theory and computation · 2023Article
- Soft Matter under Pressure: Pushing Particle-Field Molecular Dynamics to the Isobaric Ensemble.Journal of chemical information and modeling · 2023Article
- Pathways of Membrane Solubilization: A Structural Study of Model Lipid Vesicles Exposed to Classical Detergents.Langmuir : the ACS journal of surfaces and colloids · 2023Article
- A pH-Driven Small-Molecule Nanotransformer Hijacks Lysosomes and Overcomes Autophagy-Induced Resistance in Cancer.Angewandte Chemie (International ed. in English) · 2022Article
- Engineering mesoporous silica nanoparticles for drug delivery: where are we after two decades?Chemical Society reviews · 2022Review
- Methods of Liposomes Preparation: Formation and Control Factors of Versatile Nanocarriers for Biomedical and Nanomedicine Application.Pharmaceutics · 2022Review
- Foam film stratification studies probe intermicellar interactions.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
- Supramolecular Packing Drives Morphological Transitions of Charged Surfactant Micelles.Angewandte Chemie (International ed. in English) · 2020Article
- Can Polarity-Inverted Surfactants Self-Assemble in Nonpolar Solvents?The journal of physical chemistry. B · 2020Article
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
The shape and size of self-assembled structures upon local organization of their molecular building blocks are hard to predict in the presence of long-range interactions. Combining small-angle X-ray/neutron scattering data, theoretical modelling, and computer simulations, sodium dodecyl sulfate (SDS), over a broad range of concentrations and ionic strengths, was investigated. Computer simulations indicate that micellar shape changes are associated with different binding of the counterions. By employing a toy model based on point charges on a surface, and comparing it to experiments and simulations, it is demonstrated that the observed morphological changes are caused by symmetry breaking of the irreducible building blocks, with the formation of transient surfactant dimers mediated by the counterions that promote the stabilization of cylindrical instead of spherical micelles. The present model is of general applicability and can be extended to all systems controlled by the presence of mobile charges.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.