ArticleAngewandte Chemie (International ed. in English)2020
Inducing Social Self-Sorting in Organic Cages To Tune The Shape of The Internal Cavity.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 28 papers.
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Who cites it
28 citing papers in PubMed.
- From triangles to squares - chiral, overcrowded polyimine macrocycles of significant chiroptical response enable the capture of chlorinated solvents.Scientific reports · 2026Article
- A self-assembled macrocycle with a non-closed structure for hierarchically upgraded self-assembly.Chemical science · 2026Article
- Enabling technology for accelerated discovery of supramolecular materials.Chemical science · 2025Review
- Low Symmetry Cage Complexes Formed by Metalation of Symmetric Hexa-Cationic Organic Cages.Angewandte Chemie (International ed. in English) · 2025Article
- Structural control of dynamic covalent cages: kineticChemical science · 2025Article
- Enhancing the Photoswitching Properties ofJournal of the American Chemical Society · 2025Article
- Novel Europium-Grafted 3D Covalent Organic Framework for Selective and Sensitive Fluorescence-Enhanced Detection of Levofloxacin.Sensors (Basel, Switzerland) · 2025Article
- Kinetic Trapping of Rylene Diimide Covalent Organic Cages.The Journal of organic chemistry · 2025Article
- Social Self-Sorting of Quasi-Racemates: A Unique Approach for Dual-Pore Molecular Crystals.Journal of the American Chemical Society · 2024Article
- Exploration of the polymorphic solid-state landscape of an amide-linked organic cage using computation and automation.Chemical communications (Cambridge, England) · 2024Article
- Constitutional adaptation to pChemical science · 2024Article
- Programmable synthesis of organic cages with reduced symmetry.Chemical science · 2024Article
- Triamine and Tetramine Edge-Length Matching Drives Heteroleptic Triangular and Tetragonal Prism Assembly.Journal of the American Chemical Society · 2024Article
- Systematic exploration of accessible topologies of cage moleculesChemical science · 2023Article
- Queer in Chem: Q&A with Professor Anna G. Slater.Communications chemistry · 2023Article
- Dynamic covalent self-assembly and self-sorting processes in the formation of imine-based macrocycles and macrobicyclic cages.Chemical science · 2023Article
- Purely Covalent Molecular Cages and Containers for Guest Encapsulation.Chemical reviews · 2022Review
- Enantioselective assembly and recognition of heterochiral porous organic cages deduced from binary chiral components.Chemical science · 2022Article
- Beyond Platonic: How to Build Metal-Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes.Chemical reviews · 2022Review
- Materials Precursor Score: Modeling Chemists' Intuition for the Synthetic Accessibility of Porous Organic Cage Precursors.Journal of chemical information and modeling · 2021Article
Corrections and comments
- Erratum issued
Authors and funding
14 authors.
Funding
Abstract
Many interesting target guest molecules have low symmetry, yet most methods for synthesising hosts result in highly symmetrical capsules. Methods of generating lower symmetry pores are thus required to maximise the binding affinity in host-guest complexes. Herein, we use mixtures of tetraaldehyde building blocks with cyclohexanediamine to access low-symmetry imine cages. Whether a low-energy cage is isolated can be correctly predicted from the thermodynamic preference observed in computational models. The stability of the observed structures depends on the geometrical match of the aldehyde building blocks. One bent aldehyde stands out as unable to assemble into high-symmetry cages-and the same aldehyde generates low-symmetry socially self-sorted cages when combined with a linear aldehyde. We exploit this finding to synthesise a family of low-symmetry cages containing heteroatoms, illustrating that pores of varying geometries and surface chemistries may be reliably accessed through computational prediction and self-sorting.
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