ArticleAngewandte Chemie (International ed. in English)2020
Quantifying Through-Space Substituent Effects.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
16 citing papers in PubMed.
- Towards next generation enzyme mimics through local electric field control in organic cage catalysts.Chemical science · 2026Article
- Probing Attractive OH-π Interactions and Repulsive n-π Interactions in a Phenol Molecular Balance.Chemistry, an Asian journal · 2026Article
- Collective Electrostatics vs through-Space Interactions: Electronic Properties of Molecules with Multiple Polar Substituents.ACS physical chemistry Au · 2026Article
- Solvation strategies for free-energy calculations in a halogen-bonded complex: implicit, explicit, and machine learning approaches.Chemical science · 2025Article
- Making Sense of Heteroatom Effects in π-π Interactions.Journal of the American Chemical Society · 2025Article
- Revisiting the Hunter-Sanders Model for π-π Interactions.Journal of the American Chemical Society · 2025Article
- Unveiling Repulsion in Intramolecular H-Bonded Systems.Journal of the American Chemical Society · 2025Article
- Striking Impact of Solvent Polarity on the Strength of Hydrogen-Bonded Complexes: A Nexus Between Theory and Experiment.Angewandte Chemie (International ed. in English) · 2025Article
- Probing Non-Covalent Interactions through Molecular Balances: A REG-IQA Study.Molecules (Basel, Switzerland) · 2024Article
- The interplay between hydrogen and halogen bonding: substituent effects and their role in the hydrogen bond enhanced halogen bond.Chemical science · 2023Article
- PET recycling under mild conditionsChemical science · 2023Article
- Dissecting Solvent Effects on Hydrogen Bonding.Angewandte Chemie (International ed. in English) · 2022Article
- ElectrostaticChemical science · 2022Article
- Dissection of the Polar and Non-Polar Contributions to Aromatic Stacking Interactions in Solution.Angewandte Chemie (International ed. in English) · 2021Article
- Modulating the radical reactivity of phenyl radicals with the help of distonic charges: it is all about electrostatic catalysis.Chemical science · 2021Article
- Quantifying Through-Space Substituent Effects.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
The description of substituents as electron donating or withdrawing leads to a perceived dominance of through-bond influences. The situation is compounded by the challenge of separating through-bond and through-space contributions. Here, we probe the experimental significance of through-space substituent effects in molecular interactions and reaction kinetics. Conformational equilibrium constants were transposed onto the Hammett substituent constant scale revealing dominant through-space substituent effects that cannot be described in classic terms. For example, NO
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.