ArticleJournal of the American Chemical Society2020
Enantioselective Si-H Insertion Reactions of Diarylcarbenes for the Synthesis of Silicon-Stereogenic Silanes.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
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Who cites it
23 citing papers in PubMed, 129 citations in OpenAlex.
- Enantioselective Synthesis of Spirolactones and Spirolactams Under Low Catalyst Loadings.Journal of the American Chemical Society · 2026Article
- Rh-catalyzed enantioselective hydrosilylation of unactivated alkenes.Chemical science · 2025Article
- Copper-catalyzed intermolecular Regio- and Enantioselective Hydrosilylation of Alkenes with Prochiral Silanes.Nature communications · 2025Article
- DigiChemTree enables programmable light-induced carbene generation for on demand chemical synthesis.Communications chemistry · 2024Article
- Organocatalytic asymmetric synthesis of Si-stereogenic silacycles.Nature communications · 2024Article
- Organocatalytic Asymmetric Synthesis of Si-Stereogenic Siloxanols.ACS catalysis · 2024Article
- Rh(II)-Catalyzed Si-H Insertion with Nosyl-hydrazone-Protected Aryl Donor Diazo Compounds.ACS omega · 2023Article
- "Sandwich" Diimine-Copper Catalyzed Trifluoroethylation and Pentafluoropropylation of Unactivated C(spChemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Enantioconvergent construction of stereogenic silicon via Lewis base-catalyzed dynamic kinetic silyletherification of racemic chlorosilanes.Nature communications · 2023Article
- Enantioselective Synthesis of Triarylmethanes via Intermolecular C-H Functionalization of Cyclohexadienes with Diaryldiazomethanes.Organic letters · 2023Article
- An unusual autocatalysis with an air-stable Pd complex to promote enantioselective synthesis of Si-stereogenic enynes.Chemical science · 2023Article
- Recent Progress in Cyclic Aryliodonium Chemistry: Syntheses and Applications.Chemical reviews · 2023Review
- X-H Bond Insertion Promoted by Heterogeneous Dirhodium Metal-Organic Cage with Alkynes as Safe Carbene Precursors.Molecules (Basel, Switzerland) · 2023Article
- "Sandwich" Diimine-Copper Catalysts for C-H Functionalization by Carbene Insertion.Angewandte Chemie (International ed. in English) · 2022Article
- Organocatalytic Asymmetric Synthesis of Si-Stereogenic Silyl Ethers.Journal of the American Chemical Society · 2022Article
- Proton or Carbene Transfer? On the Dark and Light Reaction of Diazoalkanes with Alcohols.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Divergent stereochemical outcomes in the insertion of donor/donor carbenes into the C-H bonds of stereogenic centers.Chemical science · 2022Article
- Nickel(ii)-catalyzed reductive silylation of alkenyl methyl ethers for the synthesis of alkyl silanes.RSC advances · 2021Article
- Dirhodium(ii)-catalysed cycloisomerization of azaenyne: rapid assembly of centrally and axially chiral isoindazole frameworks.Chemical science · 2021Article
- Photochemical Carbene Transfer Reactions of Aryl/Aryl Diazoalkanes-Experiment and Theory*.Angewandte Chemie (International ed. in English) · 2021Article
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4 authors at 1 institution in 1 country.
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Abstract
We report the first example of enantioselective, intermolecular diarylcarbene insertion into Si-H bonds for the synthesis of silicon-stereogenic silanes. Dirhodium(II) carboxylates catalyze an Si-H insertion using carbenes derived from diazo compounds where selective formation of an enantioenriched silicon center is achieved using prochiral silanes. Fourteen prochiral silanes were evaluated with symmetrical and prochiral diazo reactants to produce a total of 25 novel silanes. Adding an ortho substituent on one phenyl ring of a prochiral diazo enhances enantioselectivity up to 95:5 er with yields up to 98%. Using
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