ArticleAngewandte Chemie (International ed. in English)2020
The Carbonyl⋅⋅⋅Tellurazole Chalcogen Bond as a Molecular Recognition Unit: From Model Studies to Supramolecular Organic Frameworks.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Visible light-induced single bond rotation in azoarenes triggered by self-sensitized oxidation.Chemical science · 2026Article
- A Substrate-Dependent Redox Catalysis of Tellurenyl Species Involving Oxidation States +I, +II, and +IV.Inorganic chemistry · 2026Article
- Supramolecular 3D Polymers Created via Chalcogen Bonding Using Benzotellurazoles as Planar Recognition Units.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Chalcogen-Guided Control of Azoarene Photoswitching: Tuning Excited-State Energies Through Electronic Property Modulation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Supramolecular Chalcogen-Bonded Shape Memory Actuators.Angewandte Chemie (International ed. in English) · 2025Article
- Supramolecular Self-Assembly of Engineered Polyproline Helices.ACS macro letters · 2023Article
- Evidence for and evaluation of fluorine-tellurium chalcogen bonding.Chemical science · 2023Article
- A Reversibly Porous Supramolecular Peptide Framework.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Chalcogen bonds: Hierarchical ab initio benchmark and density functional theory performance study.Journal of computational chemistry · 2021Article
- A Quantitative Molecular Orbital Perspective of the Chalcogen Bond.ChemistryOpen · 2021Article
- The Nature of Strong Chalcogen Bonds Involving Chalcogen-Containing Heterocycles.Angewandte Chemie (International ed. in English) · 2020Article
- The Carbonyl⋅⋅⋅Tellurazole Chalcogen Bond as a Molecular Recognition Unit: From Model Studies to Supramolecular Organic Frameworks.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
4 authors.
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Abstract
In the last years, chalcogen bonding, the noncovalent interaction involving chalcogen centers, has emerged as interesting alternative to the ubiquitous hydrogen bonding in many research areas. Here, we could show by means of high-level quantum chemical calculations that the carbonyl⋅⋅⋅tellurazole chalcogen bond is at least as strong as conventional hydrogen bonds. Using the carbonyl⋅⋅⋅tellurazole binding motif, we were able to design complex supramolecular networks in solid phase starting from tellurazole-substituted cyclic peptides. X-ray analyses reveal that the rigid structure of the cyclic peptides is caused by hydrogen bonds, whereas the supramolecular network is held together by chalcogen bonding. The type of the supramolecular network depends on peptide used; both linear wires and a honeycomb-like supramolecular organic framework (SOF) were observed. The unique structure of the SOF shows two channels filled with different types of solvent mixtures that are either locked or freely movable.
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