ArticleJournal of the American Chemical Society2020
Ni(I)-Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
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Who cites it
23 citing papers in PubMed, 95 citations in OpenAlex.
- Ligand Arm Length Governs Geometry, Spin State, and Reactivity in Unsymmetrical β-Diketiminato Nickel(II) and Nickel(I) Complexes.Inorganic chemistry · 2026Article
- 2-Substituted vs 2,9-Disubstituted Phenanthroline-NiInorganic chemistry · 2025Article
- Discovery of NiJournal of the American Chemical Society · 2025Article
- Rapid Oxygen Atom Transfer at a Catalysis-Relevant Ni(I)-Alkyl Complex with NJournal of the American Chemical Society · 2025Article
- The mechanism of acetyl-CoA synthase through the lens of a nickel model system.Nature communications · 2025Article
- Proximal and Remote Hydrocarboxylation of Alkenes with Carbon Dioxide Enabled by Nickel-Catalyzed Hydrogen Atom Transfer.Angewandte Chemie (International ed. in English) · 2025Article
- Evidence for a Unifying NiJournal of the American Chemical Society · 2025Article
- Repurposing First-Row Transition Metal Carbon Dioxide Reduction Electrocatalysts for Electrochemical Carboxylation of Benzyl Chloride.ACS organic & inorganic Au · 2024Article
- Ni-catalysed remote C(spNature reviews. Chemistry · 2024Review
- Nickel-Catalyzed Hydrocarboxylation of Terminal Unactivated Alkenes: Formation of Branched Carboxylic Acids and Competing Catalyst Deactivation from COOrganometallics · 2024Article
- Ni(2,2':6',2''-terpyridine)Dalton transactions (Cambridge, England : 2003) · 2024Article
- Effect of 6,6'-Substituents on Bipyridine-Ligated Ni Catalysts for Cross-Electrophile Coupling.ACS catalysis · 2024Article
- Kinetically-Controlled Ni-Catalyzed Direct Carboxylation of Unactivated Secondary Alkyl Bromides without Chain Walking.Journal of the American Chemical Society · 2024Article
- Straightforward synthesis of functionalized γ-Lactams using impure CONature communications · 2023Article
- Ligand Redox Activity of Organonickel Radical Complexes Governed by the Geometry.Journal of the American Chemical Society · 2023Article
- Synthesis of Nickel(I)-Bromide Complexes via Oxidation and Ligand Displacement: Evaluation of Ligand Effects on Speciation and Reactivity.Journal of the American Chemical Society · 2023Article
- Comparative study of COChemical science · 2023Article
- Elucidating electron-transfer events in polypyridine nickel complexes for reductive coupling reactions.Nature catalysis · 2023Article
- Ni/Photoredox-Catalyzed C(spJournal of the American Chemical Society · 2022Article
- Electrocatalysis with Molecular Transition-Metal Complexes for Reductive Organic Synthesis.JACS Au · 2022Review
Corrections and comments
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Authors and funding
6 authors at 4 institutions in 3 countries.
Funding
Abstract
Although the catalytic carboxylation of unactivated alkyl electrophiles has reached remarkable levels of sophistication, the intermediacy of (phenanthroline)Ni(I)-alkyl species-complexes proposed in numerous Ni-catalyzed reductive cross-coupling reactions-has been subject to speculation. Herein we report the synthesis of such elusive (phenanthroline)Ni(I) species and their reactivity with CO
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.