ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
Catalytic Transfer Hydrogenation of Arenes and Heteroarenes.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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The trial behind it
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Who cites it
8 citing papers in PubMed.
- Late-Stage Saturation of Drug Molecules.Journal of the American Chemical Society · 2024Article
- Facile Transfer Hydrogenation of N-Heteroarenes and Nitroarenes Using Magnetically Recoverable Pd@SPIONs Catalyst.ACS omega · 2024Article
- Iridium-catalyzed asymmetricChemical science · 2022Article
- Asymmetric Full Saturation of Vinylarenes with Cooperative Homogeneous and Heterogeneous Rhodium Catalysis.Journal of the American Chemical Society · 2021Article
- Amine-Boranes as Transfer Hydrogenation and Hydrogenation Reagents: A Mechanistic Perspective.Angewandte Chemie (International ed. in English) · 2021Review
- Substituted Dihydropyridine Synthesis by Dearomatization of Pyridines.Angewandte Chemie (International ed. in English) · 2021Article
- Reducing Challenges in Organic Synthesis with Stereoselective Hydrogenation and Tandem Catalysis.Journal of the American Chemical Society · 2021Article
- Catalytic Transfer Hydrogenation of Arenes and Heteroarenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Transfer hydrogenation reactions are of great interest to reduce diverse molecules under mild reaction conditions. To date, this type of reaction has only been successfully applied to alkenes, alkynes and polarized unsaturated compounds such as ketones, imines, pyridines, etc. The reduction of benzene derivatives by transfer hydrogenation has never been described, which is likely due to the high energy barrier required to dearomatize these compounds. In this context, we have developed a catalytic transfer hydrogenation reaction for the reduction of benzene derivatives and heteroarenes to form complex 3-dimensional scaffolds bearing various functional groups at room temperature without needing compressed hydrogen gas.
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Registered trials
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