ArticleJournal of the American Chemical Society2020
Transport Phenomena: Challenges and Opportunities for Molecular Catalysis in Metal-Organic Frameworks.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.
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Who cites it
27 citing papers in PubMed, 128 citations in OpenAlex.
- Metal organic semiconducting structures for electronic band engineering and optoelectronic uses.iScience · 2026Review
- Measuring Electrode Kinetics Under Spatial Confinement. Application of Pulse Voltammetry to Different Mass Transport Modes Using Butler-Volmer and Marcus-Hush-Chidsey Frameworks.ACS measurement science au · 2026Article
- Instability of PCN-224(Fe) during the oxygen reduction reaction; metal-organic framework electrocatalysts may have an Achilles heel.Chemical science · 2026Article
- Photo-Driven COChemSusChem · 2026Article
- Insights and advances of theranostic nanoscale metal-organic frameworks.Mikrochimica acta · 2025Review
- Rapid Redox Hopping Charge Transfer and Electrochromism in a Multivariate Metal-Organic Framework.Journal of the American Chemical Society · 2025Article
- Supramolecular Materials and Strategies for Bioorthogonal Chemical Transformations.Chemical reviews · 2025Review
- Molecular Electrocatalysis in Confined Spaces: Analysis of the Cyclic Staircase and Cyclic Voltammetry Responses.ACS electrochemistry · 2025Article
- Switching between Limiting Charge Extraction Regimes in an Illuminated Semiconductor-Metal-Organic Framework Junction.Journal of the American Chemical Society · 2025Article
- Evaluating the Origins of Aerobic Oxidation Catalysis with TAM-3, a MOF with Accessible Co(II) Sites and Large Pores.ACS catalysis · 2025Article
- The Role of Metal-Organic Framework Induced Confinement Effects on Molecular Electrocatalysts Relevant to the Energy Transition.ChemSusChem · 2025Review
- Effect of the Electrolyte on the Oxygen Reduction Reaction with a MOF Embedded Co-Porphyrin.ChemSusChem · 2025Article
- The Molecular Nature of Redox-Conductive Metal-Organic Frameworks.Accounts of chemical research · 2024Article
- Diffusional Electron Transport Coupled to Thermodynamically Driven Electron Transfers in Redox-Conductive Multivariate Metal-Organic Frameworks.Journal of the American Chemical Society · 2024Article
- Electrochromism in Isoreticular Metal-Organic Framework Thin Films with Record High Coloration Efficiency.ACS nano · 2023Article
- Synthetic styrene-based bioinspired model of the [FeFe]-hydrogenase active site for electrocatalytic hydrogen evolution.Sustainable energy & fuels · 2023Article
- Experimental manifestation of redox-conductivity in metal-organic frameworks and its implication for semiconductor/insulator switching.Nature communications · 2023Article
- Molecular Catalysis of Energy Relevance in Metal-Organic Frameworks: From Higher Coordination Sphere to System Effects.Chemical reviews · 2023Review
- Chemically routed interpore molecular diffusion in metal-organic framework thin films.Nature communications · 2023Article
- Role of molecular modelling in the development of metal-organic framework for gas adsorption applications.Journal of chemical sciences (Bangalore, India) · 2023Review
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Metal-organic frameworks (MOFs) are appealing heterogeneous support matrices that can stabilize molecular catalysts for the electrochemical conversion of small molecules. However, moving from a homogeneous environment to a porous film necessitates the transport of both charge and substrate to the catalytic sites in an efficient manner. This presents a significant challenge in the application of such materials at scale, since these two transport phenomena (charge and mass transport) would need to operate faster than the intrinsic catalytic rate in order for the system to function efficiently. Thus, understanding the fundamental kinetics of MOF-based molecular catalysis of electrochemical reactions is of crucial importance. In this Perspective, we quantitatively dissect the interplay between the two transport phenomena and the catalytic reaction rate by applying models from closely related fields to MOF-based catalysis. The identification of the limiting process provides opportunities for optimization that are uniquely suited to MOFs due to their tunable molecular structure. This will help guide the rational design of efficient and high-performing catalytic MOF films with incorporated molecular catalyst for electrochemical energy conversion.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.