ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
Rapid Organocatalytic Formation of Carbon Monoxide: Application towards Carbonylative Cross Couplings.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed.
- Computer Vision Enables Monitoring and Kinetic Analysis of Structurally Diverse Carbon Monoxide Surrogates.Angewandte Chemie (International ed. in English) · 2026Article
- Synthesis of Unsymmetrical Ketones Using Chelation-Controlled Sequential Substitution ofACS omega · 2022Article
- Light-Activated CO Donor as a Universal CO Surrogate for Pd-Catalyzed and Light-Mediated Carbonylation.Organic letters · 2022Article
- Base-promoted direct amidation of esters: beyond the current scope and practical applications.RSC advances · 2022Article
- A Journey from June 2018 to October 2021 withMolecules (Basel, Switzerland) · 2021Review
- Rapid Organocatalytic Formation of Carbon Monoxide: Application towards Carbonylative Cross Couplings.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Herein, the first organocatalytic method for the transformation of non-derivatized formic acid into carbon monoxide (CO) is introduced. Formylpyrrolidine (FPyr) and trichlorotriazine (TCT), which is a cost-efficient commodity chemical, enable this decarbonylation. Utilization of dimethylformamide (DMF) as solvent and catalyst even allows for a rapid CO generation at room temperature. Application towards four different carbonylative cross coupling protocols demonstrates the high synthetic utility and versatility of the new approach. Remarkably, this also comprehends a carbonylative Sonogashira reaction at room temperature employing intrinsically difficult electron-deficient aryl iodides. Commercial
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Registered trials
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