ArticlePolymers2020
Ultra-High Through-Cure of (Meth)Acrylate Copolymers via Photofrontal Polymerization.
Article in Polymers, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
9 citing papers in PubMed.
- UV-cure hydrogels for cardiac regeneration: a comprehensive review.Stem cell research & therapy · 2025Review
- Tailoring UV Penetration Depth in Photopolymer Nanocomposites: Advancing SLA 3D Printing Performance with Nanofillers.Polymers · 2025Article
- Synergistic Dual-Cure Reactions for the Fabrication of Thermosets by Chemical Heating.ACS sustainable chemistry & engineering · 2024Article
- Frontal Polymerizations: From Chemical Perspectives to Macroscopic Properties and Applications.Chemical reviews · 2023Review
- Photoinitiator Selection and Concentration in Photopolymer Formulations towards Large-Format Additive Manufacturing.Polymers · 2022Article
- Review
- Recent Advances inMolecules (Basel, Switzerland) · 2021Review
- Resins for Frontal Photopolymerization: Combining Depth-Cure and Tunable Mechanical Properties.Materials (Basel, Switzerland) · 2021Article
- 3D Printed Ultrastretchable, Hyper-Antifreezing Conductive Hydrogel for Sensitive Motion and Electrophysiological Signal Monitoring.Research (Washington, D.C.) · 2020Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Photopolymerization offers substantial advantages in terms of time, temperature, energy consumption, and spatial control of the initiation. The application however is strongly limited due to the constrained penetration of light into thick films. Strategies to overcome the problem of limited curing depth, as well as to improve the curing of shadow areas, involve dual curing, frontal polymerization, and upconversion of particles. Whereas excellent results have been accomplished applying photofrontal polymerization on a theoretical level, few studies report on practical applications achieving high curing depth within short time. This study aims to investigate the potential of photofrontal polymerization, performed only with photoinitiator and light, for the fast and easy production of several-centimeter-thick (meth)acrylic layers. Monomer/ initiator systems were evaluated with respect to their optical density as well as photobleaching behavior. Moreover, depth-dependent polymerization was studied in specimens of varying monomer ratio and photoinitiator concentration. When an ideal photoinitiator concentration was selected, curing up to 52 mm in depth was accomplished within minutes.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.