ArticleAngewandte Chemie (International ed. in English)2020
Chemical Reaction Monitoring using Zero-Field Nuclear Magnetic Resonance Enables Study of Heterogeneous Samples in Metal Containers.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
18 citing papers in PubMed, 43 citations in OpenAlex.
- Enabling nondestructive observation of electrolyte composition in batteries with ultralow-field nuclear magnetic resonance.Chemical science · 2026Article
- Indirect Zero-Field Nuclear Magnetic Resonance Spectroscopy.Analytical chemistry · 2025Article
- Article
- NMR Relaxation to Probe Zeolites: Mobility of Adsorbed Molecules, Surface Acidity, Pore Size Distribution and Connectivity.Molecules (Basel, Switzerland) · 2024Review
- Zero-field J-spectroscopy of quadrupolar nuclei.Nature communications · 2024Article
- Enzymatic Reactions Observed with Zero- and Low-Field Nuclear Magnetic Resonance.Analytical chemistry · 2023Article
- Detection of pyridine derivatives by SABRE hyperpolarization at zero field.Communications chemistry · 2023Article
- Real-Time Reaction Monitoring of Azide-Alkyne Cycloadditions Using Benchtop NMR-Based Signal Amplification by Reversible Exchange (SABRE).ACS measurement science au · 2023Article
- Spin Hyperpolarization in Modern Magnetic Resonance.Chemical reviews · 2023Review
- Relayed hyperpolarization for zero-field nuclear magnetic resonance.Science advances · 2022Article
- Interfacing Liquid State Hyperpolarization Methods with NMR Instrumentation.Journal of magnetic resonance open · 2022Article
- Recent advances in the application of parahydrogen in catalysis and biochemistry.RSC advances · 2022Review
- Instrumentation for Hydrogenative Parahydrogen-Based Hyperpolarization Techniques.Analytical chemistry · 2022Article
- Zero-Field NMR of Urea: Spin-Topology Engineering by Chemical Exchange.The journal of physical chemistry letters · 2021Article
- Ultrafast Laplace NMR to study metal-ligand interactions in reversible polarisation transfer from parahydrogen.Physical chemistry chemical physics : PCCP · 2021Article
- Bridging the Gap: From Homogeneous to Heterogeneous Parahydrogen-induced Hyperpolarization and Beyond.Chemphyschem : a European journal of chemical physics and physical chemistry · 2021Review
- Zero-Field NMRThe journal of physical chemistry letters · 2021Article
- Chemical Reaction Monitoring using Zero-Field Nuclear Magnetic Resonance Enables Study of Heterogeneous Samples in Metal Containers.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
8 authors at 2 institutions in 3 countries.
Funding
Abstract
We demonstrate that heterogeneous/biphasic chemical reactions can be monitored with high spectroscopic resolution using zero-field nuclear magnetic resonance spectroscopy. This is possible because magnetic susceptibility broadening is negligible at ultralow magnetic fields. We show the two-step hydrogenation of dimethyl acetylenedicarboxylate with para-enriched hydrogen gas in conventional glass NMR tubes, as well as in a titanium tube. The low frequency zero-field NMR signals ensure that there is no significant signal attenuation arising from shielding by the electrically conductive sample container. This method paves the way for in situ monitoring of reactions in complex heterogeneous multiphase systems and in reactors made of conductive materials while maintaining resolution and chemical specificity.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.