ArticleAngewandte Chemie (International ed. in English)2020
Unilaterally Fluorinated Acenes: Synthesis and Solid-State Properties.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
8 citing papers in PubMed.
- Shape control in 2D molecular nanosheets by tuning anisotropic intermolecular interactions and assembly kinetics.Nature communications · 2023Article
- Regioselective Fluorination of Acenes: Tailoring of Molecular Electronic Levels and Solid-State Properties.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Article
- Diazapentacenes from Quinacridones.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Engineering of TMDC-OSC hybrid interfaces: the thermodynamics of unitary and mixed acene monolayers on MoSChemical science · 2020Article
- Unilaterally Fluorinated Acenes: Synthesis and Solid-State Properties.Angewandte Chemie (International ed. in English) · 2020Article
- Impact of fluorination on interface energetics and growth of pentacene on Ag(111).Beilstein journal of nanotechnology · 2020Article
- Synthesis of 6,13-difluoropentacene.Beilstein journal of organic chemistry · 2020Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
9 authors.
Funding
Abstract
The rapid development of organic electronics is closely related to the availability of molecular materials with specific electronic properties. Here, we introduce a novel synthetic route enabling a unilateral functionalization of acenes along their long side, which is demonstrated by the synthesis of 1,2,10,11,12,14-hexafluoropentacene (1) and the related 1,2,9,10,11-pentafluorotetracene (2). Quantum chemical DFT calculations in combination with optical and X-ray absorption spectroscopy data indicate that the single-molecule properties of 1 are a connecting link between the organic semiconductor model systems pentacene (PEN) and perfluoropentacene (PFP). In contrast, the crystal structure analysis reveals a different packing motif than for the parent molecules. This can be related to distinct F⋅⋅⋅H interactions identified in the corresponding Hirshfeld surface analysis and also affects solid-state properties such as the exciton binding energy and the sublimation enthalpy.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.