ArticleThe journal of physical chemistry letters2020
Resonance Raman Optical Activity Shows Unusual Structural Sensitivity for Systems in Resonance with Multiple Excited States: Vitamin B
Article in The journal of physical chemistry letters, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Article
- Monitoring the Switching from Base-on to Base-off Forms of Vitamin BAnalytical chemistry · 2026Article
- Why Does One Measure Resonance Raman Optical Activity? A Unique Case of Measurements under Strong Resonance versus Far-from-Resonance Conditions.The journal of physical chemistry letters · 2024Article
- Resonance Raman analysis of intracellular vitamin BAnalytical science advances · 2022Article
- Quantum interference directed chiral raman scattering in two-dimensional enantiomers.Nature communications · 2022Article
- Anharmonicity and Spectra-Structure Correlations in MIR and NIR Spectra of Crystalline Menadione (Vitamin KMolecules (Basel, Switzerland) · 2021Article
- Recognition of the True and False Resonance Raman Optical Activity.Angewandte Chemie (International ed. in English) · 2021Article
- Resonance Raman Optical Activity Spectroscopy in Probing Structural Changes Invisible to Circular Dichroism Spectroscopy: A Study on Truncated Vitamin BMolecules (Basel, Switzerland) · 2020Article
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Authors and funding
6 authors.
Funding
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Abstract
In this work, cobalamins with different upper axial substituents and a cobalamin derivative with a ring modification were studied using chiroptical spectroscopies, in particular resonance Raman optical activity (RROA), to shed light on the influence of structural modifications on RROA spectra in these strongly chiral systems in resonance with multiple excited states at 532 nm excitation. We have demonstrated that for these unique systems RROA possesses augmented structural specificity, surpassing resonance Raman spectroscopy and enabling at the same time measurement of cobalamins at fairy low concentrations of ∼10
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