ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
The Earlier the Better: Structural Analysis and Separation of Lanthanides with Pyrroloquinoline Quinone.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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14 citing papers in PubMed, 38 citations in OpenAlex.
- Source-Independent Enrichment of Light Lanthanides: Microbial Mobilization, Selective Uptake, and Intracellular Storage.Environmental microbiology · 2026Article
- Urban Biomining of Rare Earth Elements: Current Status and Future Opportunities.ACS environmental Au · 2026Review
- Hybrid Lanthanide Metal-Organic Compounds with Flavonoids: Magneto-Optical Properties and Biological Activity Profiles.International journal of molecular sciences · 2025Article
- A novel in-silico model explores LanM homologs among Hyphomicrobium spp.Communications biology · 2024Article
- Identification and characterization of a small-molecule metallophore involved in lanthanide metabolism.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Rare earth elements in biology: From biochemical curiosity to solutions for extractive industries.Microbial biotechnology · 2024Review
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- Lanmodulin peptides - unravelling the binding of the EF-Hand loop sequences stripped from the structural corset.Inorganic chemistry frontiers · 2022Article
- Americium preferred: lanmodulin, a natural lanthanide-binding protein favors an actinide over lanthanides.Chemical science · 2021Article
- A Natural Lanthanide-Binding Protein Facilitates Separation and Recovery of Rare Earth Elements.ACS central science · 2021Article
- Pyrroloquinoline Quinone Aza-Crown Ether Complexes as Biomimetics for Lanthanide and Calcium Dependent Alcohol Dehydrogenases*.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Crystal structure of a calcium(II)-pyrroloquinoline quinone (PQQ) complex outside a protein environment.Acta crystallographica. Section C, Structural chemistry · 2020Article
- The Earlier the Better: Structural Analysis and Separation of Lanthanides with Pyrroloquinoline Quinone.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
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Authors and funding
11 authors at 4 institutions in 1 country.
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Abstract
Lanthanides (Ln) are critical raw materials, however, their mining and purification have a considerable negative environmental impact and sustainable recycling and separation strategies for these elements are needed. In this study, the precipitation and solubility behavior of Ln complexes with pyrroloquinoline quinone (PQQ), the cofactor of recently discovered lanthanide (Ln) dependent methanol dehydrogenase (MDH) enzymes, is presented. In this context, the molecular structure of a biorelevant europium PQQ complex was for the first time elucidated outside a protein environment. The complex crystallizes as an inversion symmetric dimer, Eu
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