Evidence map›Paper›PMID 32488940›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020

Triphenylphosphine-Based Covalent Organic Frameworks and Heterogeneous Rh-P-COFs Catalysts.

Yubing Liu, Alla Dikhtiarenko, Naizhang Xu, Jiawei Sun, Jie Tang, Kaiqiang Wang, Bolian Xu, Qing Tong, Hero Jan Heeres, Songbo He and 2 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Yubing LiuKey Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, Nanjing, 2100093, P. R. China.
Alla DikhtiarenkoKAUST Catalysis Center, Advanced Catalytic Materials, King Abdullah University of Science and Technology, Thuwal, 23955, Saudi Arabia.
Naizhang XuKey Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, Nanjing, 2100093, P. R. China.
Jiawei SunKey Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, Nanjing, 2100093, P. R. China.
Jie TangKey Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, Nanjing, 2100093, P. R. China.
Kaiqiang WangKey Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, Nanjing, 2100093, P. R. China.
Bolian XuKey Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, Nanjing, 2100093, P. R. China.
Qing TongKey Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, Nanjing, 2100093, P. R. China.
Hero Jan HeeresGreen Chemical Reaction Engineering, University of Groningen, 9747 AG, Groningen, The Netherlands.
Songbo HeGreen Chemical Reaction Engineering, University of Groningen, 9747 AG, Groningen, The Netherlands.
Jorge GasconKAUST Catalysis Center, Advanced Catalytic Materials, King Abdullah University of Science and Technology, Thuwal, 23955, Saudi Arabia.
Yining FanKey Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, Nanjing, 2100093, P. R. China.ORCID http://orcid.org/0000-0003-1212-8258

Funding

National Natural Science Foundation of China 21773107Netherlands Organization for Scientific Research NWO-LIFT Programme Grant No.731.016.401
6 · The paper itself

Abstract

The synthesis of phosphine-based functional covalent organic frameworks (COFs) has attracted great attention recently. Herein, we present two examples of triphenylphosphine-based COFs (termed P-COFs) with well-defined crystalline structures, high specific surface areas, and good thermal stability. Furthermore, rhodium catalysts with these P-COFs as support material show high turnover frequency for the hydroformylation of olefins, as well as excellent recycling performance. This work not only extends the phosphine-based COF family, but also demonstrates their application in immobilizing homogeneous metal-based (e.g., Rh-phosphine) catalysts for application in heterogeneous catalysis.

Indexed as

covalent organic frameworksheterogeneous catalystsolefin hydroformylationtriphenylphosphine

Identifiers

PMID32488940
PMCPMC7540510

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.