ArticlePolymers2020
Highly Effective Sensitizers Based on Merocyanine Dyes for Visible Light Initiated Radical Polymerization.
Article in Polymers, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Highly Efficient Photoinitiation Systems Based on Dibenzo[a,c]phenazine Sensitivity to Visible Light for Dentistry.Materials (Basel, Switzerland) · 2024Article
- The Influence of the Alkylamino Group on the Solvatochromic Behavior of 5-(4-substituted-arylidene)-1,3-dimethylpyrimidine-2,4,6-triones: Synthesis, Spectroscopic and Computational Studies.Materials (Basel, Switzerland) · 2024Article
- Design of Dyes Based on the Quinoline or Quinoxaline Skeleton towards Visible Light Photoinitiators.International journal of molecular sciences · 2024Article
- Study on New Dental Materials Containing Quinoxaline-Based Photoinitiators in Terms of Exothermicity of the Photopolymerization Process.International journal of molecular sciences · 2023Article
- A Modified Oxazolone Dye Dedicated to Spectroscopy and Optoelectronics.The Journal of organic chemistry · 2022Article
- Acenaphthoquinoxaline Derivatives as Dental Photoinitiators of Acrylates Polymerization.Materials (Basel, Switzerland) · 2021Article
- Effective Singlet Oxygen Sensitizers Based on the Phenazine Skeleton as Efficient Light Absorbers in Dye Photoinitiating Systems for Radical Polymerization of Acrylates.Materials (Basel, Switzerland) · 2021Article
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2 authors.
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Abstract
The 5-(4-substituted-arylidene)-1,3-dimethylpyrimidine-2,4,6-triones were tested as visible light sensitizers for phenyltrialkylborate salts applied to initiate polymerization processes. The initiation occurs as a result of photoinduced electron transfer from the borate salt to the merocyanine dye. The main factor that facilitates the step of the reaction is the free energy change for electron transfer. Its value is favorable according to the reduction properties of the dyes influenced by the type of amino groups and the oxidation potentials of the borate salts. The observed bleaching of the dyes during photopolymerization affects the yield of both the alkyl radical and sensitizer-based radical formation and thus the efficiency of the photopolymerization.
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