ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
Versatile Visible-Light-Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
17 citing papers in PubMed.
- Article
- Electron Donor-Acceptor Chromophore Assembly as an Enabling Process for the Overall Light-Driven Reduction of Phosphine Oxides.Organic letters · 2026Article
- Harnessing Pnictogen and Chalcogen Bonding for Cross-Electrophile C-POrganic letters · 2026Article
- Closing the Loop: Low-Waste Phosphorus Functionalization Enabled by Simple Disulfides.ChemSusChem · 2025Article
- Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations.Chemical reviews · 2025Review
- Adduct-catalyzed tandem electro-thermal synthesis of organophosphorus (III) compounds from white phosphorus.National science review · 2025Article
- Direct carbonyl reductive functionalizations by diphenylphosphine oxide.Science advances · 2025Article
- Mechanistic Insights and Synthetic Explorations of the Photoredox-Catalyzed Activation of Halophosphines.Inorganic chemistry · 2023Article
- Photocatalytic stannylation of white phosphorus.Chemical communications (Cambridge, England) · 2022Article
- Recent Breakthroughs in PAngewandte Chemie (International ed. in English) · 2022Review
- Nickel-catalysed diversification of phosphine ligands by formal substitution at phosphorus.Chemical science · 2022Article
- Photochemical transformation of chlorobenzenes and white phosphorus into arylphosphines and phosphonium salts.Chemical communications (Cambridge, England) · 2022Article
- Photocatalytic Arylation of PAngewandte Chemie (International ed. in English) · 2021Article
- Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus.Nature communications · 2021Article
- Synthesis of monophosphines directly from white phosphorus.Nature chemistry · 2021Article
- Easy Access to Enantiomerically Pure Heterocyclic Silicon-Chiral Phosphonium Cations and the Matched/Mismatched Case of Dihydrogen Release.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Versatile Visible-Light-Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
8 authors.
Funding
Abstract
Asymmetrically substituted tertiary phosphines and quaternary phosphonium salts are used extensively in applications throughout industry and academia. Despite their significance, classical methods to synthesize such compounds often demand either harsh reaction conditions, prefunctionalization of starting materials, highly sensitive organometallic reagents, or expensive transition-metal catalysts. Mild, practical methods thus remain elusive, despite being of great current interest. Herein, we describe a visible-light-driven method to form these products from secondary and primary phosphines. Using an inexpensive organic photocatalyst and blue-light irradiation, arylphosphines can be both alkylated and arylated using commercially available organohalides. In addition, the same organocatalyst can be used to transform white phosphorus (P
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.