ArticleNature communications2020
A cyclic bis[2]catenane metallacage.
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- One Coordination Cage, Many Pathways: Multiple Stimuli Drive Reversible Transformations.JACS Au · 2026Article
- Observation of Near-Infrared Photothermal and Photoacoustic Effects in a Metallosupramolecular Trefoil Knot.Angewandte Chemie (International ed. in English) · 2025Article
- A Robust Heterometallic PtAngewandte Chemie (International ed. in English) · 2025Article
- Cooperative reversible assembly in triply interlocked AlChemical science · 2025Article
- Emerging mechanically interlocked cages.Nature reviews. Chemistry · 2025Review
- Mechanical interlocking of metal organic cages.Communications chemistry · 2025Review
- Multiple-stimuli fluorescent responsive metallo-organic helicated cage arising from monomer and excimer emission.Nature communications · 2024Article
- Formation of a low-symmetry PdChemical science · 2024Article
- The effect of host size on binding in host-guest complexes of cyclodextrins and polyoxometalates.Chemical science · 2024Article
- Cross-catenation between position-isomeric metallacages.Nature communications · 2024Article
- Heterochiral Diastereomer-Discriminative Diphanes That Form Hierarchical Superstructures with Nonlinear Optical Properties.JACS Au · 2022Article
- Transformation networks of metal-organic cages controlled by chemical stimuli.Chemical Society reviews · 2022Review
- Mechanically interlocked molecular handcuffs.Chemical science · 2022Review
- Syntheses of three-dimensional catenanes under kinetic control.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- A class of organic cages featuring twin cavities.Nature communications · 2021Article
Corrections and comments
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Authors and funding
13 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Catenated cages represent chemistry's challenging synthetic targets because a three-dimensional assembly is necessary for their formation. Herein, a cyclic bis[2]catenane is constructed through the coordination-driven self-assembly of the interlocked bis-metallacage, by the 90° Pt(II) heteroligation of the endo-functionalized double-bridged tweezer bearing pyridyl moieties and the tetra-carboxylated linker. NMR spectrometry, X-ray crystallography and mass spectrometry confirm the formation of a cyclic bis[2]catenane with "∞"-shaped topology via a 14-component self-assembly. Particularly, reversibly responsive transformation between the bis[2]catenane and the bis-metallacage can be realized by guest exchange, concentration effect and solvent effect. This work represents a novel example of a cyclic cage-based [2]catenane oligomer.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.