ArticleJournal of the American Chemical Society2020
Catalytic and Photochemical Strategies to Stabilized Radicals Based on Anomeric Nucleophiles.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
10 citing papers in PubMed.
- Direct radical functionalization of native sugars.Nature · 2024Article
- Dehydroxylative radical N-glycosylation of heterocycles with 1-hydroxycarbohydrates enabled by copper metallaphotoredox catalysis.Nature communications · 2024Article
- Transformations of carbohydrate derivatives enabled by photocatalysis and visible light photochemistry.Chemical science · 2024Review
- Photosensitizer-free visible-light-promoted glycosylation enabled by 2-glycosyloxy tropone donors.Nature communications · 2023Article
- Stereoselective alkylChemical science · 2023Article
- Synthesis ofChemical science · 2021Article
- Light-Mediated Cross-Coupling of Anomeric Trifluoroborates.Organic letters · 2021Article
- Diastereoselective Synthesis of Aryl C-Glycosides from Glycosyl Esters via C-O Bond Homolysis.Angewandte Chemie (International ed. in English) · 2021Article
- Direct, stereoselective thioglycosylation enabled by an organophotoredox radical strategy.Chemical science · 2020Article
- Stereochemistry of Transition Metal Complexes Controlled by the Metallo-Anomeric Effect.Journal of the American Chemical Society · 2020Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Carbohydrates, one of the three primary macromolecules of living organisms, play significant roles in various biological processes such as intercellular communication, cell recognition, and immune activity. While the majority of established methods for the installation of carbohydrates through the anomeric carbon rely on nucleophilic displacement, anomeric radicals represent an attractive alternative because of their functional group compatibility and high anomeric selectivities. Herein, we demonstrate that anomeric nucleophiles such as C1 stannanes can be converted into anomeric radicals by merging Cu(I) catalysis with blue light irradiation to achieve highly stereoselective C(sp
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Registered trials
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