ArticleAngewandte Chemie (International ed. in English)2020
Activation of a Metal-Halogen Bond by Halogen Bonding.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
25 citing papers in PubMed.
- Functionalized Fluorescein for Rapid and Colorimetric Assay of Pirimicarb via Halogen and Hydrogen Bonding Synergistic Effect.Molecules (Basel, Switzerland) · 2026Article
- Halogen bonding-induced 1,3-carbohydroxylation of allyl carboxylatesChemical science · 2026Article
- Spirosilanes Activate Gold(I)-Catalysts in Cycloisomerization and Intermolecular Reactions.Angewandte Chemie (International ed. in English) · 2026Article
- Asymmetric synthesis of β-amino cyanoesters with contiguous tetrasubstituted carbon centers by halogen-bonding catalysis with chiral halonium salt.Beilstein journal of organic chemistry · 2025Article
- Hydrogen-Bonding Activation of Gold(I) Chloride Complexes: Enantioselective Synthesis of 3(2Organic letters · 2024Article
- Evaluating the halogen bonding strength of a iodoloisoxazolium(III) salt.Beilstein journal of organic chemistry · 2024Article
- Poly-pnictogen bonding: trapping halide ions by a tetradentate antimony(iii) Lewis acid.Chemical science · 2023Article
- Halogen Bond-Involving Self-Assembly of Iodonium Carboxylates: Adding a Dimension to Supramolecular Architecture.International journal of molecular sciences · 2023Article
- Binding, Sensing, And Transporting Anions with Pnictogen Bonds: The Case of Organoantimony Lewis Acids.Journal of the American Chemical Society · 2023Review
- Cyclic Homo- and Heterohalogen Di-λJournal of the American Chemical Society · 2023Article
- Exploring Au(i) involving halogen bonding with N-heterocyclic carbene Au(i) aryl complexes in crystalline media.Chemical science · 2023Article
- Silver-Free Gold-Catalyzed Heterocyclizations through Intermolecular H-Bonding Activation.The Journal of organic chemistry · 2023Article
- Recent Progress in Cyclic Aryliodonium Chemistry: Syntheses and Applications.Chemical reviews · 2023Review
- Exploring the role of halogen bonding in iodonium ylides: insights into unexpected reactivity and reaction control.Beilstein journal of organic chemistry · 2023Review
- Stacking Interactions: A Supramolecular Approach to Upgrade Weak Halogen Bond Donors.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Halogen Bond Motifs in Cocrystals ofCrystal growth & design · 2022Article
- Chalcogen bond-guided conformational isomerization enables catalytic dynamic kinetic resolution of sulfoxides.Nature communications · 2022Article
- Evaluation of Halogenopyridinium Cations as Halogen Bond Donors.Crystal growth & design · 2021Article
- N-Heterocyclic Iod(az)olium Salts - Potent Halogen-Bond Donors in Organocatalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Silver-Free Au(I) Catalysis Enabled by Bifunctional Urea- and Squaramide-Phosphine Ligands via H-Bonding.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
8 authors.
Funding
Abstract
In recent years, the non-covalent interaction of halogen bonding (XB) has found increasing application in organocatalysis. However, reports of the activation of metal-ligand bonds by XB have so far been limited to a few reactions with elemental iodine or bromine. Herein, we present the activation of metal-halogen bonds by two classes of inert halogen bond donors and the use of the resulting activated complexes in homogenous gold catalysis. The only recently explored class of iodolium derivatives were shown to be effective activators in two test reactions and their activity could be modulated by blocking of the Lewis acidic sites. Bis(benzimidazolium)-based halogen bonding activators provided even more rapid conversion, while the non-iodinated reference compound showed little activity. The role of halogen bonding in the activation of metal-halogen bonds was further investigated by NMR experiments and DFT calculations, which support the mode of activation occurring via halogen bonding.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.