ArticleInorganic chemistry frontiers2020
Hydrogen Peroxide Disproportionation with Manganese Macrocyclic Complexes of Cyclen and Pyclen.
Article in Inorganic chemistry frontiers, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed, 22 citations in OpenAlex.
- Antioxidant Potential of a Non-Heme Iron Complex: Mitigating HInorganic chemistry · 2026Article
- Tailoring Antioxidant Activities: Metal-Type Dependent, Highly Active SOD or Catalase Mimetics.Inorganic chemistry · 2025Article
- Predicting pRSC advances · 2025Article
- Advances in the synthesis and applications of macrocyclic polyamines.Royal Society open science · 2024Review
- Hydrogen Peroxide Disproportionation Activity Is Sensitive to Pyridine Substitutions on Manganese Catalysts Derived from 12-Membered Tetra-Aza Macrocyclic Ligands.Inorganic chemistry · 2023Article
- Synthesis and characterization of two piperazine containing macrocycles and their transition metal complexes.Journal of inorganic biochemistry · 2023Article
- Manganese (III/IV) μ-Oxo Dimers and Manganese (III) Monomers with Tetraaza Macrocyclic Ligands and Historically Relevant Open-Chain Ligands.European journal of inorganic chemistry · 2022Article
- Sustainable hydrogen production from water using tandem dye-sensitized photoelectrochemical cells.Nano convergence · 2021Review
- Manganese Complex of a Rigidified 15-Membered Macrocycle: A Comprehensive Study.Inorganic chemistry · 2020Article
Corrections and comments
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Authors and funding
8 authors at 3 institutions in 1 country.
Funding
Abstract
The catalase family of enzymes, which include a variety with a binuclear manganese active site, mitigate the risk from reactive oxygen species by facilitating the disproportionation of hydrogen peroxide into molecular oxygen and water. In this work, hydrogen peroxide disproportionation using complexes formed between manganese and cyclen or pyclen were investigated due to the spectroscopic similarities with the native MnCAT enzyme. Potentiometric titrations were used to construct speciation diagrams that identify the manganese complex compositions at different pH values. Each complex behaves as a functional mimic of catalase enzymes. UV-visible spectroscopic investigations of the H
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Registered trials
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