ReviewMolecules (Basel, Switzerland)2020
Stereochemistry of Simple Molecules inside Nanotubes and Fullerenes: Unusual Behavior of Usual Systems.
Review in Molecules (Basel, Switzerland), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
5 citing papers in PubMed.
- A new selenium nanomaterial: structural insights, nonlinear optical properties (DFT study), and biological potential.Journal of molecular modeling · 2025Article
- Deciphering the Reactive Pathways of Competitive Reactions inside Carbon Nanotubes.Nanomaterials (Basel, Switzerland) · 2022Article
- Snapshots of the Fragmentation for CInternational journal of molecular sciences · 2021Article
- Structural and Conformational Aspects in the Chemistry of Heterocycles.Molecules (Basel, Switzerland) · 2020Article
- Molecular Structure Modulated Trap Distribution and Carrier Migration in Fluorinated Epoxy Resin.Molecules (Basel, Switzerland) · 2020Article
Corrections and comments
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Authors and funding
1 author.
Funding
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Abstract
Over the past three decades, carbon nanotubes and fullerenes have become remarkable objects for starting the implementation of new models and technologies in different branches of science. To a great extent, this is defined by the unique electronic and spatial properties of nanocavities due to the ramified π-electron systems. This provides an opportunity for the formation of endohedral complexes containing non-covalently bonded atoms or molecules inside fullerenes and nanotubes. The guest species are exposed to the force field of the nanocavity, which can be described as a combination of electronic and steric requirements. Its action significantly changes conformational properties of even relatively simple molecules, including ethane and its analogs, as well as compounds with C-O, C-S, B-B, B-O, B-N, N-N, Al-Al, Si-Si and Ge-Ge bonds. Besides that, the cavity of the host molecule dramatically alters the stereochemical characteristics of cyclic and heterocyclic systems, affects the energy of pyramidal nitrogen inversion in amines, changes the relative stability of cis and trans isomers and, in the case of chiral nanotubes, strongly influences the properties of
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Registered trials
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