ArticleNature communications2020
Rapidly sequence-controlled electrosynthesis of organometallic polymers.
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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Who cites it
9 citing papers in PubMed.
- Article
- Molecular HDD logic for encrypted massive data storage.Nature communications · 2025Article
- Atomic-Scale Imaging of Polymers and Precision Molecular Weight Analysis.Journal of the American Chemical Society · 2024Article
- Surface-confined alternating copolymerization with molecular precision by stoichiometric control.Nature communications · 2024Article
- Composition and sequence-controlled conductance of crystalline unimolecular monolayers.Science advances · 2023Article
- Synthesis of Phosphorus(V)-Substituted Six-MemberedMolecules (Basel, Switzerland) · 2023Review
- Paramagnetic encoding of molecules.Nature communications · 2022Article
- Pathway-Dependent Coordination Networks: Crystals versus Films.Journal of the American Chemical Society · 2021Article
- Regio- and sequence-controlled conjugated topological oligomers and polymers via boronate-tag assisted solution-phase strategy.Nature communications · 2021Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Single rich-stimuli-responsive organometallic polymers are considered to be the candidate for ultrahigh information storage and anti-counterfeiting security. However, their controllable synthesis has been an unsolved challenge. Here, we report the rapidly sequence-controlled electrosynthesis of organometallic polymers with exquisite insertion of multiple and distinct monomers. Electrosynthesis relies on the use of oxidative and reductive C-C couplings with the respective reaction time of 1 min. Single-monomer-precision propagation does not need protecting and deprotecting steps used in solid-phase synthesis, while enabling the uniform synthesis and sequence-defined possibilities monitored by both UV-vis spectra and cyclic voltammetry. Highly efficient electrosynthesis possessing potentially automated production can incorporate an amount of available metal and ligand species into a single organometallic polymer with complex architectures and functional versatility, which is proposed to have ultrahigh information storage and anti-counterfeiting security with low-cost coding and decoding processes at the single organometallic polymer level.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.