ArticleInorganic chemistry2020
Synthesis and Hydrosilylation of Vinyl-Substituted Open-Cage Silsesquioxanes with Phenylsilanes: Regioselective Synthesis of Trifunctional Silsesquioxanes.
Article in Inorganic chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Article
- Cobalt-Catalyzed Dehydrogenative C-H Silylation of Alkynylsilanes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Alkenyl-Functionalized Open-Cage Silsesquioxanes (RSiMeInorganic chemistry · 2021Article
- Double-Decker Silsesquioxanes Self-Assembled in One-Dimensional Coordination Polymeric Nanofibers with Emission Properties.ACS applied materials & interfaces · 2021Article
- Vinyl-Functionalized Janus Ring Siloxane: Potential Precursors to Hybrid Functional Materials.Materials (Basel, Switzerland) · 2021Article
- Formation of Bifunctional Octasilsesquioxanes via Silylative Coupling and Cross-Metathesis Reaction.Materials (Basel, Switzerland) · 2020Article
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Authors and funding
3 authors.
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Abstract
Herein, we report an efficient synthesis and functionalization of trifunctional open-cage-type silsesquioxanes. The method proposed has been successfully applied for the synthesis of a library of incompletely condensed silsesquioxanes with vinyldiorganosilyl functional groups, which allows further modification. Detailed studies of hydrosilylation of sterically different open-cage vinylsilsesquioxanes with a wide spectrum of phenylsilanes catalyzed by platinum and rhodium compounds are also reported. The influence of the reaction parameters, types of reagents, and catalysts employed on the efficiency of the process was examined. Optimization of the process based on the above results permitted the design of a very attractive method for the synthesis of multifunctionalized silsesquioxanes with excellent yields and regioselectivity. Moreover, the results allowed the choice of the most efficient catalyst whose application led to the selective formation of substituted open-cage silsesquioxanes. These new compounds have been fully characterized and studied in terms of their thermal properties.
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