Evidence map›Paper›PMID 32430860›Full record

ArticleJournal of fluorescence2020

A Spectroscopic Study of Xanthene Dyes on a Polystyrene Surface: an Investigation of Ion-π Interactions at Polymer Interfaces.

Matthew Mullen, Nolan Fontaine, William B Euler

Abstract read
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In one paragraph

Article in Journal of fluorescence, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Fluorescence in colloidal solutions: Scattering vs physicochemical effects on line shape.Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy · 2023
    Article
  2. Simultaneous removal of PbRSC advances · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Matthew MullenDepartment of Chemistry, 140 Flagg Road, Kingston, RI, 02881, USA.
Nolan FontaineDepartment of Chemistry, 140 Flagg Road, Kingston, RI, 02881, USA.
William B EulerDepartment of Chemistry, 140 Flagg Road, Kingston, RI, 02881, USA. weuler@chm.uri.edu.ORCID http://orcid.org/0000-0002-5317-8510

Funding

Science and Technology Directorate 2013-ST-061-ED0001
6 · The paper itself

Abstract

Thin films of three differently charged xanthene dyes: rhodamine 6G (Rh6G, cationic), fluorescein 27 (F27, neutral), and disodium fluorescein (DSF, anionic) were cast onto a polystyrene (PS) coated glass substrate to investigate ion-π interactions. Absorbance spectroscopy was used to determine the aggregation state of the dyes on the PS surface. Deconvolution of the spectra of films revealed multiple peaks for all dyes assigned to isolated monomers, aggregates, and complexes between the dye and the polymer substrate. The shift of the low energy peak relative to the monomer peak was used as an indication of interaction strength of that species with the PS π system, which followed the trend of Rh6G > DSF > F27. Increase in the interaction energy is attributed to stabilization from ion-π interactions. Steady-state emission spectra and excited state lifetime measurements were performed on all films. The formation of a weakly emissive exciplex was found for Rh6G and DSF, consistent with ion-π interactions, but no evidence of an exciplex is found for the F27 films.

Indexed as

InterfacesIon-pi complexesXanthene dyes

Identifiers

What OpenQuestion holds

Textmetadata
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.