ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
Dibenzothiophenesulfilimines: A Convenient Approach to Intermolecular Rhodium-Catalysed C-H Amidation.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Photo-induced selective N-N bond construction via harnessing nitrene release and transfer.Nature communications · 2026Article
- The Tribological Properties of Novel Sulfoximine Derivatives as Lubricant Additives.Materials (Basel, Switzerland) · 2024Article
- Development of Nonclassical Photoprecursors for RhInorganic chemistry · 2023Article
- An unexpected synthesis of azepinone derivatives through a metal-free photochemical cascade reaction.Nature communications · 2023Article
- Allylic Amination of Alkenes with Iminothianthrenes to Afford Alkyl Allylamines.Journal of the American Chemical Society · 2020Article
- Dibenzothiophenesulfilimines: A Convenient Approach to Intermolecular Rhodium-Catalysed C-H Amidation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
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Authors and funding
6 authors.
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Abstract
A sulfilimine-based Group 9 transition-metal-catalysed C-H amidation procedure is reported. Dibenzothiophene-based sulfilimines were shown to constitute a class of novel amidation reagents which enable the transfer of a wide range of N-sulfonyl and N-acyl moieties. It was demonstrated that sulfilimines, which are easily accessible from cheap reagents, are safe-to-handle and represent broadly applicable amidation reagents. The dibenzothiophene can be recycled after use. The C-H amidation was shown to proceed with high selectivity and gave the mono-amidated products, mostly in good to excellent yields.
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