ArticleAngewandte Chemie (International ed. in English)2020
A Heteroleptic Dirhodium Catalyst for Asymmetric Cyclopropanation with α-Stannyl α-Diazoacetate. "Stereoretentive" Stille Coupling with Formation of Chiral Quarternary Carbon Centers.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The trial behind it
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Who cites it
9 citing papers in PubMed.
- Dispersive Fluorine/Bromine Interactions as Key Selectivity Determinant: Asymmetric Cyclopropanations with 3,3,3-Trifluoro-2-diazopropionate Catalyzed by a Heterochiral-at-The-Metal Centers Dirhodium Paddlewheel Complex.Journal of the American Chemical Society · 2026Article
- Dirhodium Complexes Heterochiral-at-the-Metal Centers: An Alternative Type of Paddlewheel Catalyst for Asymmetric Synthesis.Journal of the American Chemical Society · 2025Article
- Article
- Chiral Bismuth-Rhodium Paddlewheel Complexes Empowered by London Dispersion: The C-H Functionalization Nexus.Angewandte Chemie (International ed. in English) · 2022Article
- Preparation of Chiral Enantioenriched Densely Substituted Cyclopropyl Azoles, Amines, and Ethers via Formal SMolecules (Basel, Switzerland) · 2022Article
- From Serendipity to Rational Design: Heteroleptic Dirhodium Amidate Complexes for Diastereodivergent Asymmetric Cyclopropanation.Journal of the American Chemical Society · 2022Article
- Triple Resonance Experiments for the Rapid Detection ofJournal of the American Chemical Society · 2021Article
- A New Ligand Design Based on London Dispersion Empowers Chiral Bismuth-Rhodium Paddlewheel Catalysts.Journal of the American Chemical Society · 2021Article
- A Heteroleptic Dirhodium Catalyst for Asymmetric Cyclopropanation with α-Stannyl α-Diazoacetate. "Stereoretentive" Stille Coupling with Formation of Chiral Quarternary Carbon Centers.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
The heteroleptic dirhodium paddlewheel catalyst 7 with a chiral carboxylate/acetamidate ligand sphere is uniquely effective in asymmetric [2+1] cycloadditions with α-diazo-α-trimethylstannyl (silyl, germyl) acetate. Originally discovered as a trace impurity in a sample of the homoleptic parent complex [Rh
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.