ArticleAngewandte Chemie (International ed. in English)2020
Iron in a Cage: Fixation of a Fe(II)tpy
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
9 citing papers in PubMed, 25 citations in OpenAlex.
- Novel metallo-supramolecular architectures based on side-pyridine-modified terpyridines: design, self-assembly, and properties.Chemical science · 2025Review
- Spin-State Switching of Spin-Crossover Complexes on Cu(111) Evidenced by Spin-Flip Spectroscopy.Angewandte Chemie (International ed. in English) · 2024Article
- Tilted Spins in Chains of Molecular Switches on Pb(100).ACS nano · 2024Article
- Exploring the Photophysics and Photocatalytic Activity of Heteroleptic Rh(III) Transition-Metal Complexes Using High-Throughput Experimentation.Inorganic chemistry · 2024Article
- Defying the inverse energy gap law: a vacuum-evaporable Fe(ii) low-spin complex with a long-lived LIESST state.Chemical science · 2023Article
- Scaling of quantum interference from single molecules to molecular cages and their monolayers.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Depositing Molecular Graphene Nanoribbons on Ag(111) by Electrospray Controlled Ion Beam Deposition: Self-Assembly and On-Surface Transformations.Angewandte Chemie (International ed. in English) · 2022Article
- Spin Crossover in a Cobalt Complex on Ag(111).Angewandte Chemie (International ed. in English) · 2022Article
- Iron in a Cage: Fixation of a Fe(II)tpyAngewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
10 authors at 4 institutions in 5 countries.
Funding
Abstract
The coordination sphere of the Fe(II) terpyridine complex 1 is rigidified by fourfold interlinking of both terpyridine ligands. Profiting from an octa-aldehyde precursor complex, the ideal dimensions of the interlinking structures are determined by reversible Schiff-base formation, before irreversible Wittig olefination provided the rigidified complex. Reversed-phase HPLC enables the isolation of the all-trans isomer of the Fe(II) terpyridine complex 1, which is fully characterized. While temperature independent low-spin states were recorded with superconducting quantum interference device (SQUID) measurements for both, the open precursor 8 and the interlinked complex 1, evidence of the increased rigidity of the ligand sphere in 1 was provided by proton T
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.