ArticleDental materials : official publication of the Academy of Dental Materials2020
Alternative monomer for BisGMA-free resin composites formulations.
Article in Dental materials : official publication of the Academy of Dental Materials, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
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Who cites it
28 citing papers in PubMed, 67 citations in OpenAlex.
- Clinical performance of single shade universal resin composites: a randomized controlled one year follow-up study.BMC oral health · 2025Trial
- Effect of effervescent multivitamin solutions on the color stability of contemporary resin composites: an in vitro study.Biomaterial investigations in dentistry · 2026Article
- Evaluation of Internal and Marginal Shrinkage Stress in Adhesive Class III Cavities Restored with Different Resin Composite Combinations-A 3D-FEA Study.Dentistry journal · 2025Article
- Evolution of Dental Resin Adhesives-A Comprehensive Review.Journal of functional biomaterials · 2025Review
- The effect of different adhesive strategies and diamond burs on dentin bond strength of universal resin cements.Clinical oral investigations · 2025Article
- The Effect of Inorganic Filler Content on the Properties of BPA-Free Bulk-Fill Dental Resin Composites.Materials (Basel, Switzerland) · 2024Article
- Effect of Stearyl Methacrylate Comonomer on the Mechanical and Physical Properties of Dimethacrylate-Based Dental Resins.Materials (Basel, Switzerland) · 2024Article
- Dental biomaterials redefined: molecular docking and dynamics-driven dental resin composite optimization.BMC oral health · 2024Article
- Multi-Parameter Characterization of HEMA/BPA-free 1- and 2-step Universal Adhesives Bonded to Dentin.The journal of adhesive dentistry · 2024Article
- In vitro characterization of a novel resin-based restorative material containing alkaline fillers.Journal of applied oral science : revista FOB · 2024Article
- Analysis of color stability and degree of conversion of different types of resin composites.Brazilian oral research · 2024Article
- Physicochemical properties of flowable composites using isobornyl methacrylate as diluent monomer.Journal of applied oral science : revista FOB · 2024Article
- Physical-Chemical and Microhardness Properties of Model Dental Composites Containing 1,2-Bismethacrylate-3-eugenyl Propane Monomer.Biomimetics (Basel, Switzerland) · 2023Article
- Polymer Mixtures for Experimental Self-Limited Dental Burs Development-A Preliminary Approach (Part 1).Journal of functional biomaterials · 2023Article
- Tailoring the monomers to overcome the shortcomings of current dental resin composites - review.Biomaterial investigations in dentistry · 2023Review
- Determination of Water Content in Direct Resin Composites Using Coulometric Karl Fischer Titration.Materials (Basel, Switzerland) · 2022Article
- Assessment of Micro-Hardness, Degree of Conversion, and Flexural Strength for Single-Shade Universal Resin Composites.Polymers · 2022Article
- Meta-analytical analysis on components released from resin-based dental materials.Clinical oral investigations · 2022Review
- Article
- Triacrylamide-Based Adhesives Stabilize Bonds in Physiologic Conditions.Journal of dental research · 2022Article
Corrections and comments
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Authors and funding
7 authors at 1 institution in 1 country.
Funding
Abstract
objectiveWater sorption, high volumetric shrinkage, polymerization stress, and potential estrogenic effects triggered by leached compounds are some of the major concerns related to BisGMA-TEGDMA co-monomer systems used in dental composites. These deficiencies call for the development of alternative organic matrices in order to maximize the clinical lifespan of resin composite dental restorations. This study proposes BisGMA-free systems based on the combination of UDMA and a newly synthesized diurethane dimethacrylate, and evaluates key mechanical and physical properties of the resulting materials.
methods2EMATE-BDI (2-hydroxy-1-ethyl methacrylate) was synthesized by the reaction between 2-hydroxy-1-ethyl methacrylate with a difunctional isocyanate (1.3-bis (1- isocyanato-1-methylethylbenzene) - BDI). The compound was copolymerized with UDMA (urethane dimethacrylate) at 40 and 60wt%. UDMA copolymerizations with 40 and 60wt% TEGDMA (triethylene glycol dimethacrylate) were tested as controls, as well as a formulation based in BisGMA (bisphenol A-glycidyl methacrylate)-TEGDMA 60:40% (BT). The organic matrices were made polymerizable by the addition of DMPA (2.2-dimethoxyphenoxy acetophenone) and DPI-PF6 (diphenyliodonium hexafluorophosphate) at 0.2 and 0.4wt%, respectively. Formulations were tested as composite with the addition of 70wt% inorganic content consisting of barium borosilicate glass (0.7μm) and fumed silica mixed in 95 and 5wt%, respectively. All photocuring procedures were carried out by a mercury arc lamp filtered to 320-500nm at 800mW/cm
resultsIn general, the addition of 2EMATE-BDI into the formulations decreased the maximum rate of polymerization (RP SIGNIFICANCE: The use of the newly synthesized diurethane dimethacrylate as co-monomer in dental resin composite formulations seems to be a promising option to develop polymers with low-shrinkage and potentially decreased water degradation.
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Registered trials
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