ArticleNature communications2020
Transient-axial-chirality controlled asymmetric rhodium-carbene C(sp
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
What it found
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The trial behind it
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Who cites it
16 citing papers in PubMed.
- Catalytic Asymmetric Spiroannulation to Access Polycyclic Spiro Enones via Transient Axial-to-Point Chirality Induction and Transfer.Nature communications · 2026Article
- Metal-free carbenoid C-H insertion: a versatile strategy for constructing fluorenes with quaternary carbon centers.Molecular diversity · 2026Article
- Access to Fluorene-Fused Isoquinolones Containing an Axially Chiral Element via Cascade Bi-Annulation Reaction of Indene-Dienes.Precision chemistry · 2026Article
- Characterization of a Silver Vinylcarbene Intermediate in Carbene-Alkyne Metathesis and Its Concerted C(spJournal of the American Chemical Society · 2026Article
- Skeletal Rearrangement of Biaryls via Rhodium-Azirine Intermediate: A Route to Solid-State Emissive Polycyclic Sulfamates.ACS catalysis · 2026Article
- Enantioselective Assembly of Fully Substituted α-Amino Allenoates Through a Mannich Addition and Stepwise [3,3]-σ Rearrangement Sequence.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Assembly of the Tricyclic Core of Alopecurone C by Asymmetric Donor/Donor Carbene C-H Insertion.Organic letters · 2024Article
- Catalytic 4-exo-dig carbocyclization for the construction of furan-fused cyclobutanones and synthetic applications.Nature communications · 2023Article
- Gold-catalyzed carbocyclization and imidization of alkyne-tethered diazo compounds with nitrosoarenes for the synthesis of nitrones and naphthalene derivatives.Molecular diversity · 2023Article
- Intramolecular Interception of the Remote Position of Vinylcarbene Silver Complex Intermediates by C(spAngewandte Chemie (International ed. in English) · 2023Article
- Palladium-catalyzed intramolecular enantioselective C(spChemical science · 2022Article
- Recent Advances in Catalytic Alkyne Transformation via Copper Carbene Intermediates.Molecules (Basel, Switzerland) · 2022Review
- RhChemical science · 2022Article
- Dirhodium(ii)-catalysed cycloisomerization of azaenyne: rapid assembly of centrally and axially chiral isoindazole frameworks.Chemical science · 2021Article
- Transition Metal Catalyzed Insertion Reactions with Donor/Donor Carbenes.Angewandte Chemie (International ed. in English) · 2021Review
- Gold(I)-catalyzed intramolecular cyclization/intermolecular cycloaddition cascade as a fast track to polycarbocycles and mechanistic insights.Nature communications · 2021Article
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
In catalytic asymmetric reactions, the formation of chiral molecules generally relies on a direct chirality transfer (point or axial chirality) from a chiral catalyst to products in the stereo-determining step. Herein, we disclose a transient-axial-chirality transfer strategy to achieve asymmetric reaction. This method relies on transferring point chirality from the catalyst to a dirhodium carbene intermediate with axial chirality, namely a transient-axial-chirality since this species is an intermediate of the reaction. The transient chirality is then transferred to the final product by C(sp
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.