ArticlePolymers2020
Curing Kinetic Analysis of Acrylate Photopolymer for Additive Manufacturing by Photo-DSC.
Article in Polymers, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed, 71 citations in OpenAlex.
- Physics-Informed Optimization for the Sub-Feature-Scale Fabrication of Hollow Microneedles via Digital Light Processing.Micromachines · 2026Article
- Modeling the thermal behavior of photopolymers for in-space fabrication.NPJ microgravity · 2026Article
- Additive manufacturing for Dentistry: A comprehensive review of techniques and applications.Progress in materials science · 2026Article
- Ethylene-Vinyl Acetate Copolymer as a Polyfunctional Modifier for Low-Viscosity Photosensitive Compositions.Polymers · 2025Article
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- Synergistic Fire Resistance of Nanobrick Wall Coated 3D Printed Photopolymer Lattices.ACS applied materials & interfaces · 2023Article
- A Review of 3D Printing Technology in Pharmaceutics: Technology and Applications, Now and Future.Pharmaceutics · 2023Review
- Temperature Controlled Mechanical Reinforcement of Polyacrylate Films Containing Nematic Liquid Crystals.Polymers · 2022Article
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- Photoinitiator Selection and Concentration in Photopolymer Formulations towards Large-Format Additive Manufacturing.Polymers · 2022Article
- Review
- Analysis of UV Curing Strategy on Reaction Heat Control and Part Accuracy for Additive Manufacturing.Polymers · 2022Article
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- 3D/4D Printing of Polymers: Fused Deposition Modelling (FDM), Selective Laser Sintering (SLS), and Stereolithography (SLA).Polymers · 2021Review
- Preparation of Bis[(3-ethyl-3-methoxyoxetane)propyl]diphenylsilane and Investigation of Its Cationic UV-Curing Material Properties.Polymers · 2021Article
- Influence of UV Polymerization Curing Conditions on Performance of Acrylic Pressure Sensitive Adhesives.Macromolecular research · 2021Article
- Double Role of Diphenylpyridine Derivatives as Fluorescent Sensors for Monitoring Photopolymerization and the Determination of the Efficiencies of the Generation of Superacids by Cationic Photoinitiators.Sensors (Basel, Switzerland) · 2020Article
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
In this research, the curing degree of an acrylate-based monomer using direct UV-assisted writing technology was characterized by differential photo calorimetry (Photo-DSC) to investigate the curing behavior. Triggered by the UV light, the duo function group monomer 1,6-Hexamethylene diacrylate (HDDA), photoinitiator 1173 and photoinhibitor exhibit a fast curing process. The exothermal photopolymerization reaction was performed in the isothermal mode in order to evaluate the different thermal effects that occurred during the photopolymerization process. The influences of both UV light intensity and exposure time were studied with single-factor analysis. The results obtained by photo-DSC also allow us to perform the kinetic study of the polymerization process: The results show that, for the reaction, the higher the UV intensity, the higher the curing degree together with faster curing speed. At the same time, the effect of the heat released during the exothermic reaction is negligible for the polymerization process. When increasing the exposure time, limited improvement of curing degree was shown, and the distribution is between 65-75%. The reaction enthalpy and related curing degree work as a function of time. The Avrami theory of phase change was introduced to describe the experimental data. The functions of a curing degree with light intensity and exposure time were achieved, respectively.
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