ArticleAngewandte Chemie (International ed. in English)2020
Precision Molecular Threading/Dethreading.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
22 citing papers in PubMed.
- The interlocking process in molecular machines explained by a combined approach: the nudged elastic band method and machine learning potential.Chemical science · 2026Article
- Programmable molecular dethreading towards tunable drug release.Nature communications · 2025Article
- Article
- Kinetic Control of Threading and Dethreading in Linked Rotaxanes via Hydrogen Bonding.Chemistry, an Asian journal · 2025Article
- Macrocycle Unidirectional Transport Along a Linear Molecule by a Two-Step Chemical Reaction Sequence.ChemistryOpen · 2025Article
- Non-threaded and rotaxane-type threaded wheel-axle assemblies consisting of dinickel(II) metallomacrocycle and dibenzylammonium axle.Communications chemistry · 2024Article
- Studying Cation Exchange in {CrChemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- Kinetically controlled synthesis of rotaxane geometric isomers.Chemical science · 2024Article
- Cyclodextrin-based rotaxanes for polymer materials: challenge on simultaneous realization of inexpensive production and defined structures.Beilstein journal of organic chemistry · 2024Review
- Photoactivated Artificial Molecular Motors.JACS Au · 2023Review
- An Operative Electrostatic Slipping Mechanism along Macrocycle Flexibility Accelerates Guest Sliding during pseudo-Rotaxane Formation.ChemistryOpen · 2022Article
- Metastable doubly threaded [3]rotaxanes with a large macrocycle.Chemical science · 2022Article
- Size-dependent compression of threaded alkyldiphosphate in head to head cyclodextrin [3]pseudorotaxanes.Chemical science · 2022Article
- Photochemical Energy Conversion with Artificial Molecular Machines.Energy & fuels : an American Chemical Society journal · 2021Review
- Direct synthetic routes to functionalised crown ethers.Organic chemistry frontiers : an international journal of organic chemistry · 2021Review
- High five! Methyl probes at five ring positions of phenylalanine explore the hydrophobic core dynamics of zinc finger miniproteins.Chemical science · 2021Article
- Stereodynamics ofChem · 2021Article
- Artificial Supramolecular Pumps Powered by Light.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Second-Generation Light-Fueled Supramolecular Pump.Journal of the American Chemical Society · 2021Article
- Motorized Macrocycle: A Photo-responsive Host with Switchable and Stereoselective Guest Recognition.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
11 authors.
Funding
Abstract
The general principles guiding the design of molecular machines based on interlocked structures are well known. Nonetheless, the identification of suitable molecular components for a precise tuning of the energetic parameters that determine the mechanical link is still challenging. Indeed, what are the reasons of the "all-or-nothing" effect, which turns a molecular "speed-bump" into a stopper in pseudorotaxane-based architectures? Here we investigate the threading and dethreading processes for a representative class of molecular components, based on symmetric dibenzylammonium axles and dibenzo[24]crown-8 ether, with a joint experimental-computational strategy. From the analysis of quantitative data and an atomistic insight, we derive simple rules correlating the kinetic behaviour with the substitution pattern, and provide rational guidelines for the design of modules to be integrated in molecular switches and motors with sophisticated dynamic features.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.