Charge-Shift Bonding in Xenon Hydrides: An NBO/NRT Investigation on HXeY···HX (Y = Cl, Br, I; X = OH, Cl, Br, I, CCH, CN) via H-Xe Blue-Shift Phenomena.

Guiqiu Zhang, Yue Su, Xiaoran Zou, Lei Fu, Junjie Song, Dezhan Chen, Chuanzhi Sun

Abstract read

In one paragraph

Article in Frontiers in chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it

0cells of the map it votes in

2citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

Charge-Shift Bonding Propensity in Halogen-Bonded BXY (B Is a Small Lewis Base HMolecules (Basel, Switzerland) · 2023
Article
Complexes of HXeY with HX (Y, X = F, Cl, Br, I): Symmetry-Adapted Perturbation Theory Study and Anharmonic Vibrational Analysis.Molecules (Basel, Switzerland) · 2023
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Guiqiu ZhangKey Laboratory of Molecular and Nano Probes, College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging, Ministry of Education, Shandong Normal University, Jinan, China.

Yue SuKey Laboratory of Molecular and Nano Probes, College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging, Ministry of Education, Shandong Normal University, Jinan, China.

Xiaoran ZouKey Laboratory of Molecular and Nano Probes, College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging, Ministry of Education, Shandong Normal University, Jinan, China.

Lei FuKey Laboratory of Molecular and Nano Probes, College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging, Ministry of Education, Shandong Normal University, Jinan, China.

Junjie SongKey Laboratory of Molecular and Nano Probes, College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging, Ministry of Education, Shandong Normal University, Jinan, China.

Dezhan ChenKey Laboratory of Molecular and Nano Probes, College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging, Ministry of Education, Shandong Normal University, Jinan, China.

Chuanzhi SunKey Laboratory of Molecular and Nano Probes, College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging, Ministry of Education, Shandong Normal University, Jinan, China.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Noble-gas bonding represents curiosity. Some xenon hydrides, such as HXeY (Y = Cl, Br, I) and their hydrogen-bonded complexes HXeY···HX (Y = Cl, Br, I; X = OH, Cl, Br, I, CN, CCH), have been identified in matrixes by observing H-Xe frequencies or its monomer-to-complex blue shifts. However, the H-Xe bonding in HXeY is not yet completely understood. Previous theoretical studies provide two answers. The first one holds that it is a classical covalent bond, based on a single ionic structure H-Xe

Indexed as

blue shiftscharge-shift bondschemical bondingelectron-pair bondshypervalent moleculeNBO/NRT methodsnoble-gas hydrideresonance bonding

Identifiers

PMID32391318

DOI10.3389/fchem.2020.00277

PMCPMC7191121

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.