ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
Combining Theory and Experiment to Characterize the Voltammetric Behavior of Nickel Anodes in the Simons Process.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
7 citing papers in PubMed, 11 citations in OpenAlex.
- Nickel Foam Electrodes-A Versatile, Powerful, and Readily Available Tool in Electro-Organic Synthesis.Chemical record (New York, N.Y.) · 2026Review
- First-Principles Investigation of Adsorption of Ethene on a Twice Oxidized NiFChemphyschem : a European journal of chemical physics and physical chemistry · 2026Article
- First-Principles Study of Adsorption of CHMaterials (Basel, Switzerland) · 2024Article
- Unravelling highly oxidized nickel centers in the anodic black film formed during the Simons process byChemical science · 2024Article
- Searching for Monomeric Nickel Tetrafluoride: Unravelling Infrared Matrix Isolation Spectra of Higher Nickel Fluorides.Angewandte Chemie (International ed. in English) · 2021Article
- Conductivity and Redox Potentials of Ionic Liquid Trihalogen Monoanions [XChemistryOpen · 2021Article
- Combining Theory and Experiment to Characterize the Voltammetric Behavior of Nickel Anodes in the Simons Process.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
The Simons process, otherwise known as the electrochemical fluorination (ECF) method, is widely used in industry to electrolytically synthesize chemicals for various purposes. Even to this day, the exact mechanism of the ECF reaction remains unknown, but is believed to involve the formation of an anodic nickel fluoride film with highly oxidized nickel centers. In this study, experiments and density functional theory calculations are combined to characterize the initial anodic peak occurring at potentials typically required in an ECF cell. NiF
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Registered trials
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