ArticleAngewandte Chemie (International ed. in English)2020
Kβ X-Ray Emission Spectroscopic Study of a Second-Row Transition Metal (Mo) and Its Application to Nitrogenase-Related Model Complexes.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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15 citing papers in PubMed, 21 citations in OpenAlex.
- Evaluating Palladium 4d-to-2p X-ray Emission Spectroscopy for Characterizing Catalytically Relevant Species.Inorganic chemistry · 2026Article
- A high-energy Laue X-ray emission spectrometer at the FXE instrument at the European XFEL.Journal of synchrotron radiation · 2025Article
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- Experimentally Assessing the Electronic Structure and Spin-State Energetics in MnFe Dimers Using 1s3p Resonant Inelastic X-ray Scattering.Inorganic chemistry · 2024Article
- Determination of Uranium Central-Field Covalency with 3Journal of the American Chemical Society · 2024Article
- X-ray absorption and emission spectroscopy of NDalton transactions (Cambridge, England : 2003) · 2024Article
- PINK: a tender X-ray beamline for X-ray emission spectroscopy.Journal of synchrotron radiation · 2024Article
- Sensitivity of Kβ mainline X-ray emission to structural dynamics in iron photosensitizer.Physical chemistry chemical physics : PCCP · 2023Article
- Combining Valence-to-Core X-ray Emission and Cu K-edge X-ray Absorption Spectroscopies to Experimentally Assess Oxidation State in Organometallic Cu(I)/(II)/(III) Complexes.Journal of the American Chemical Society · 2022Article
- Selenium Valence-to-Core X-ray Emission Spectroscopy and Kβ HERFD X-ray Absorption Spectroscopy as Complementary Probes of Chemical and Electronic Structure.Inorganic chemistry · 2022Article
- Phosphorus Kβ X-ray emission spectroscopy detects non-covalent interactions of phosphate biomoleculesChemical science · 2021Article
- Revealing the bonding of solvated Ru complexes with valence-to-core resonant inelastic X-ray scattering.Chemical science · 2021Article
- New reflections on hard X-ray photon-in/photon-out spectroscopy.Nanoscale · 2020Article
- Kβ X-Ray Emission Spectroscopic Study of a Second-Row Transition Metal (Mo) and Its Application to Nitrogenase-Related Model Complexes.Angewandte Chemie (International ed. in English) · 2020Article
- Ruthenium 4d-to-2p X-ray Emission Spectroscopy: A Simultaneous Probe of the Metal and the Bound Ligands.Inorganic chemistry · 2020Article
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Authors and funding
5 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In recent years, X-ray emission spectroscopy (XES) in the Kβ (3p-1s) and valence-to-core (valence-1s) regions has been increasingly used to study metal active sites in (bio)inorganic chemistry and catalysis, providing information about the metal spin state, oxidation state and the identity of coordinated ligands. However, to date this technique has been limited almost exclusively to first-row transition metals. In this work, we present an extension of Kβ XES (in both the 4p-1s and valence-to-1s [or VtC] regions) to the second transition row by performing a detailed experimental and theoretical analysis of the molybdenum emission lines. It is demonstrated in this work that Kβ
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