ArticleNature communications2020
Exploiting racemism enhanced organic room-temperature phosphorescence to demonstrate Wallach's rule in the lighting chiral chromophores.
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 29 papers.
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Who cites it
29 citing papers in PubMed.
- Predicting room temperature phosphorescence of new organic molecules by combining physical models and data-driven methods.Chemical science · 2026Article
- Highly Dissymmetric and Multicolor Circularly Polarized Organic Hyperafterglow.Angewandte Chemie (International ed. in English) · 2026Article
- Circularly Polarized Long-Persistent and Photostimulated Luminescence Enabled through Förster Resonance Energy Transfer and Upconversion Strategies.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Polymer matrix drives thermal stimulation-caused dynamic phosphorescence in dispersed chromophores.Nature communications · 2026Article
- Luminescent Chiral Molecular Glasses by Melt-Quenching Enantiopure BINAP.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Homochiral versus Racemic 2D Covalent Organic Frameworks.Journal of the American Chemical Society · 2025Article
- Pure Hydrocarbon Hosts Enabling Efficient Multi-Resonance TADF Blue-Emitting Organic Light-Emitting Diodes.Angewandte Chemie (International ed. in English) · 2025Article
- Rational Molecular Design for Boosting Afterglow Efficiency in Nonplanar Carbazolocarbazoles.JACS Au · 2025Article
- Stimulating Chiral Selective Expression of Room Temperature Phosphorescence for Chirality Recognition.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Integration of Wallach's Rule into Intermolecular Charge Transfer: A Visual Strategy for Chiral Purification.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Delayed room temperature phosphorescence enabled by phosphines.Nature communications · 2024Article
- Tunable afterglow for mechanical self-monitoring 3D printing structures.Nature communications · 2024Article
- Highly Efficient Purely Organic Phosphorescence Light-Emitting Diodes Employing a Donor-Acceptor Skeleton with a Phenoxaselenine Donor.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Observation of Chiral-selective room-temperature phosphorescence enhancement via chirality-dependent energy transfer.Nature communications · 2023Article
- Conformation-dependent dynamic organic phosphorescence through thermal energy driven molecular rotations.Nature communications · 2023Article
- Ultra-fast triplet-triplet-annihilation-mediated high-lying reverse intersystem crossing triggered by participation of nπ*-featured excited states.Nature communications · 2022Article
- Ultralong organic phosphorescence from isolated molecules with repulsive interactions for multifunctional applications.Nature communications · 2022Article
- Clustering and halogen effects enabled red/near-infrared room temperature phosphorescence from aliphatic cyclic imides.Nature communications · 2022Article
- White Emissions Containing Room Temperature Phosphorescence from Different Excited States of a D-π-A Molecule Depending on the Aggregate States.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Article
- Structural Water Molecules Confined in Soft and Hard Nanocavities as Bright Color Emitters.ACS physical chemistry Au · 2022Article
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Authors and funding
12 authors.
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Abstract
The correlation between molecular packing structure and its room-temperature phosphorescence (RTP), hence rational promotion of the intensity, remains unclear. We herein present racemism enhanced RTP chiral chromophores by 2,2-bis-(diphenylphosphino)-1,1-napthalene (rac-BINAP) in comparison to its chiral counterparts. The result shows that rac-BINAP in crystal with denser density, consistent with a long standing Wallach's rule, exhibits deeper red RTP at 680 nm than that of the chiral counterparts. The cross packing between alternative R- and S- forms in rac-BINAP crystal significantly retards the bimolecular quenching pathway, triplet-triplet annihilation (TTA), and hence suppresses the non-radiative pathway, boosting the RTP intensity. The result extends the Wallach's rule to the fundamental difference in chiral-photophysics. In electroluminescence, rac-BINAP exhibits more balanced fluorescence versus phosphorescence intensity by comparison with that of photoluminescence, rendering a white-light emission. The result paves an avenue en route for white-light organic light emitting diodes via full exploitation of intrinsic fluorescence and phosphorescence.
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