ArticleAngewandte Chemie (International ed. in English)2020
Not Guilty on Every Count: The "Non-Innocent" Nitrosyl Ligand in the Framework of IUPAC's Oxidation-State Formalism.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Metal-Free Scission of the NOAngewandte Chemie (International ed. in English) · 2026Article
- From NO to NTe:ACS omega · 2025Article
- Tumor Niche Influences the Activity and Delivery of Anticancer Drugs: Pharmacology Meets Chemistry.Pharmaceuticals (Basel, Switzerland) · 2025Review
- Probing the Framework Metal Dependent Properties of Actinide-Centered Polyoxoalkoxide Sandwich-Type Complexes.Inorganic chemistry · 2025Article
- NO Oxidation States in Nonheme Iron Nitrosyls: A DMRG-CASSCF Study of {FeNO}Inorganic chemistry · 2025Article
- Local Oxidation States in {FeNO}Inorganic chemistry · 2023Article
- Sulfur Lone Pairs Control Topology in Heterotrimetallic Complexes: An Experimental and Theoretical Study.ACS organic & inorganic Au · 2023Article
- Iridium Complexes with BIAN-Type Ligands: Synthesis, Structure and Redox Chemistry.International journal of molecular sciences · 2023Article
- Accurate non-covalent interaction energies on noisy intermediate-scale quantum computersChemical science · 2023Article
- Reply to the 'Comment on "The oxidation state in low-valent beryllium and magnesium compounds"' by S. Pan and G. Frenking,Chemical science · 2023Article
- Pas de Deux of an NO Couple: Synchronous Photoswitching from a Double-Linear to a Double-Bent Ru(NO)Angewandte Chemie (International ed. in English) · 2022Article
- A DMRG/CASPT2 Investigation of Metallocorroles: Quantifying Ligand Noninnocence in Archetypal 3d and 4d Element Derivatives.JACS Au · 2021Article
- Unveiling the Electronic Structure of the Bi(+1)/Bi(+3) Redox Couple on NCN and NNN Pincer Complexes.Inorganic chemistry · 2021Article
- Chasing the Mond Cation: Synthesis and Characterization of the Homoleptic Nickel Tetracarbonyl Cation and its Tricarbonyl-Nitrosyl Analogue.Angewandte Chemie (International ed. in English) · 2021Article
- Beyond the Classical Electron-Sharing and Dative Bond Picture: Case of the Spin-Polarized Bond.Angewandte Chemie (International ed. in English) · 2021Article
- Quantification of Ni-N-O Bond Angles and NO Activation by X-ray Emission Spectroscopy.Inorganic chemistry · 2021Article
- Not Guilty on Every Count: The "Non-Innocent" Nitrosyl Ligand in the Framework of IUPAC's Oxidation-State Formalism.Angewandte Chemie (International ed. in English) · 2020Article
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7 authors.
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Abstract
Nitrosyl-metal bonding relies on the two interactions between the pair of N-O-π* and two of the metal's d orbitals. These (back)bonds are largely covalent, which makes their allocation in the course of an oxidation-state determination ambiguous. However, apart from M-N-O-angle or net-charge considerations, IUPAC's "ionic approximation" is a useful tool to reliably classify nitrosyl metal complexes in an orbital-centered approach.
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