Evidence map›Paper›PMID 32338429›Full record

ArticleChemSusChem2020

Selective Electrocatalytic Oxidation of Biomass-Derived 5-Hydroxymethylfurfural to 2,5-Diformylfuran: from Mechanistic Investigations to Catalyst Recovery.

Peter Kisszekelyi, Rifan Hardian, Hakkim Vovusha, Binglin Chen, Xianhai Zeng, Udo Schwingenschlögl, Jozsef Kupai, Gyorgy Szekely

Open access · hybridAbstract read
In one paragraph

Article in ChemSusChem, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.

0numbers the graph read from it
0cells of the map it votes in
16citing papers in PubMed
4.3field-weighted citation impact, top 5% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

16 citing papers in PubMed, 78 citations in OpenAlex.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 4 institutions in 4 countries.

Peter KisszekelyiDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Szent Gellert ter 4, Budapest, 1111, Hungary.ORCID http://orcid.org/0000-0002-9529-0674
Rifan HardianAdvanced Membranes and Porous Materials Center, Physical Science and Engineering Division (PSE), King Abdullah University of Science and Technology, Thuwal, 23955-6900, Saudi Arabia.ORCID http://orcid.org/0000-0003-1509-8058
Hakkim VovushaPhysical Science and Engineering Division (PSE), King Abdullah University of Science and Technology, Thuwal, 23955-6900, Saudi Arabia.ORCID http://orcid.org/0000-0002-6613-7785
Binglin ChenCollege of Energy, Xiamen University, Xiamen, 361102, P. R. China.
Xianhai ZengCollege of Energy, Xiamen University, Xiamen, 361102, P. R. China.ORCID http://orcid.org/0000-0002-5441-3164
Udo SchwingenschlöglPhysical Science and Engineering Division (PSE), King Abdullah University of Science and Technology, Thuwal, 23955-6900, Saudi Arabia.ORCID http://orcid.org/0000-0003-4179-7231
Jozsef KupaiDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Szent Gellert ter 4, Budapest, 1111, Hungary.ORCID http://orcid.org/0000-0002-4212-4517
Gyorgy SzekelyAdvanced Membranes and Porous Materials Center, Physical Science and Engineering Division (PSE), King Abdullah University of Science and Technology, Thuwal, 23955-6900, Saudi Arabia.ORCID http://orcid.org/0000-0001-9658-2452
King Abdullah University of Science and Technology · SABudapest University of Technology and Economics · HUXiamen University · CNUniversity of Manchester · GB

Funding

Magyar Tudományos Akadémia ÚNKP-19-4-BME-415
6 · The paper itself

Abstract

The catalytic transformation of bio-derived compounds, specifically 5-hydroxymethylfurfural (HMF), into value-added chemicals may provide sustainable alternatives to crude oil and natural gas-based products. HMF can be obtained from fructose and successfully converted to 2,5-diformylfuran (DFF) by an environmentally friendly organic electrosynthesis performed in an ElectraSyn reactor, using cost-effective and sustainable graphite (anode) and stainless-steel (cathode) electrodes in an undivided cell, eliminating the need for conventional precious metal electrodes. In this work, the electrocatalysis of HMF is performed by using green solvents such as acetonitrile, γ-valerolactone, as well as PolarClean, which is used in electrocatalysis for the first time. The reaction parameters and the synergistic effects of the TEMPO catalyst and 2,6-lutidine base are explored both experimentally and through computation modeling. The molecular design and synthesis of a size-enlarged C

Indexed as

biomassdiformylfuranelectrochemistryhydroxymethylfurfuralorganic solvent nanofiltration

Identifiers

PMID32338429
PMCPMC7318667
OpenAlexW3019050035

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.