ArticleJournal of the American Chemical Society2020
Visible-Light-Driven Rotation of Molecular Motors in a Dual-Function Metal-Organic Framework Enabled by Energy Transfer.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 46 papers.
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Who cites it
46 citing papers in PubMed.
- Strategies towards designing visible and near-infrared light driven molecular motors.Chemical Society reviews · 2026Review
- Protonation-Gated Orthogonal Control of Highly Efficient Molecular Motors With Broad Visible-Light Responsiveness.Angewandte Chemie (International ed. in English) · 2026Article
- NIR-II photothermal-driven pulsatile PTH release for osteoporotic bone repair.National science review · 2026Article
- Stretchable Piezoelectric Membrane of Ferroelectric Charge-Transfer Cocrystals for Efficient Energy Harvesting and Self-Powered Wearable Sensors.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Spatial Orientation-Dependent Double Hydrogen Bond/Photoredox Cooperative Catalysis in Metal-Organic Frameworks.Angewandte Chemie (International ed. in English) · 2026Article
- Enhanced Energy Transfer from a Metal-Organic Framework to a Highly Confined Organic Phosphorescent Dye.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Turn-on luminescence from molecular rotor realignment in metal-organic framework thin films.Nature communications · 2026Article
- Light-Induced Rotation of a Molecular Motor in the Confined Space of a Metal-Organic Nanocage.Journal of the American Chemical Society · 2026Article
- Design of Molecular Crystals toward Crystalline Molecular Machines: Rotors, Gears, and Motors.ACS nanoscience Au · 2025Review
- Powering Molecular Motors with Light Across the Rainbow Using Quantum Dots.Journal of the American Chemical Society · 2025Article
- Mechanism Inversion in Visible Light-Induced Photoclick Reactions.Journal of the American Chemical Society · 2025Article
- Highly Efficient Near-Infrared Light-Driven Molecular Motor Rotation Enabled by Upconversion Nanoparticles as Nanoscale Light Sources.Journal of the American Chemical Society · 2025Article
- Engineering Bodipy-Based Metal-Organic Frameworks for Efficient Full-Spectrum Photocatalysis in Amide Synthesis.Angewandte Chemie (International ed. in English) · 2025Article
- Unidirectional molecular rotary motor with remotely switchable rotation direction.Science advances · 2025Article
- Host-Guest Synergy of Metal-Organic Frameworks for Enhanced Near-Infrared Ultrafast Laser Responsiveness.ACS central science · 2025Article
- General strategy for boosting the performance of speed-tunable rotary molecular motors with visible light.Science advances · 2025Article
- Selective Separation of CInorganic chemistry · 2024Article
- Metal-Organic Framework-Based Micro-/Nanomotors for Wastewater Remediation.Small science · 2024Article
- Amplifying dual-visible-light photoswitching in aqueous mediaChemical science · 2024Article
- Confined Space Nanoarchitectonics for Dynamic Functions and Molecular Machines.Micromachines · 2024Review
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The visible-light-driven rotation of an overcrowded alkene-based molecular motor strut in a dual-function metal-organic framework (MOF) is reported. Two types of functional linkers, a palladium-porphyrin photosensitizer and a bispyridine-derived molecular motor, were used to construct the framework capable of harvesting low-energy green light to power the rotary motion. The molecular motor was introduced in the framework using the postsynthetic solvent-assisted linker exchange (SALE) method, and the structure of the material was confirmed by powder (PXRD) and single-crystal X-ray (SC-XRD) diffraction. The large decrease in the phosphorescence lifetime and intensity of the porphyrin in the MOFs upon introduction of the molecular motor pillars confirms efficient triplet-to-triplet energy transfer between the porphyrin linkers and the molecular motor. Near-infrared Raman spectroscopy revealed that the visible light-driven rotation of the molecular motor proceeds in the solid state at rates similar to those observed in solution.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.